5-BroMo-Benzo[c]phenanthrene

Base Information

• Chemical Name: 5-BroMo-Benzo[c]phenanthrene
• CAS No.: 89523-51-3
• Molecular Formula: C18H11Br
• Molecular Weight: 307.189
• Mol file: 89523-51-3.mol

Synonyms:5-BroMo-Benzo[c]phenanthrene;5-BroMo-Benzo[c]phenthrene

Chemical Property of 5-BroMo-Benzo[c]phenanthrene

Chemical Property:

• Melting Point: 76.6-77.6℃
• Boiling Point: 482.9±14.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.477±0.06 g/cm3(Predicted)
• LogP: 5.90870
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98% ^*data from raw suppliers

5-Bromobenzo[c]phenanthrene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-BroMo-Benzo[c]phenanthrene

There total 15 articles about 5-BroMo-Benzo[c]phenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

benzo[c]phenathrene (195-19-7) → 5-bromobenzophenanthrene (89523-51-3)

Guidance literature:

With copper(II) bromide supported on alumina; In tetrachloromethane; at 35 ℃; for 48h;

DOI:10.1039/a607258e

Reference yield: 48.0%

benzo[c]phenathrene (195-19-7) → 5-bromobenzophenanthrene (89523-51-3) + 5,8-dibromobenzophenanthrene (121012-73-5) + 5,7,8-tribromo-7,8-dihydrobenzophenanthrene (121012-72-4)

Guidance literature:

With bromine; Yield given. Multistep reaction; 1.) benzene, RT, 24 h, 2.) CH₃CN, reflux, 2 h;

DOI:10.1021/jo00274a026

Reference yield: 15.0%

1-bromo-4-[1-(2-methoxyvinyl)phenyl]naphthalene (1155911-74-2) → 5-bromobenzophenanthrene (89523-51-3)

Guidance literature:

With methanesulfonic acid; In dichloromethane; at 20 ℃; for 8h;

upstream raw materials:

benzo[c]phenathrene

trans-5,6-dibromo-5,6-dihydrobenzophenanthrene

trans-5-bromo-6-acetoxy-5,6-dihydrobenzophenantherene

tetrachloromethane

Downstream raw materials:

5-(diphenylamino)benzo[c]phenanthrene

9-(phenyl)-10-(benzo[c]phenanthren-5-yl)anthracene

C₃₇H₂₄N₂

benzo[c]phenathrene

Refernces

• 1、 Liu, En-Chih,Chen, Min-Kuan,Li, Jen-Yi,Wu, Yao-Ting. "Palladium-catalyzed annulation of 9-halophenanthrenes with alkynes: Synthesis, structural analysis, and properties of acephenanthrylene-based derivatives". supporting information. p. 4755 - 4761. Retrieved 2015/03/18.
• 2、 -. "NITROGENATED HETEROCYCLIC RING DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME". Page/Page column 29. . Retrieved 2012/12/13.