Stannane, tributyl[(methylsulfonyl)oxy]-

Base Information

• Chemical Name: Stannane, tributyl[(methylsulfonyl)oxy]-
• CAS No.: 13302-06-2
• Molecular Formula: C13H30O3SSn
• Molecular Weight: 385.18
• DSSTox Substance ID: DTXSID0074504
• NSC Number: 221196
• Mol file: 13302-06-2.mol

Synonyms:13302-06-2;Tributylstannyl methanesulfonate;Stannane, tributyl[(methylsulfonyl)oxy]-;Tri-n-butyltin methanesulfonate;Stannane, ((methylsulfonyl)oxy)tributyl-;Stannane, tributyl((methylsulfonyl)oxy)-;Methanesulfonic acid, tributylstannyl ester;Stannane, [(methylsulfonyl)oxy]tributyl-;Tin, tributyl-, methanesulfonate;NSC 221196;BRN 3962207;Tin, methanesulfonate;DTXSID0074504;TRIBUTYLTIN METHANESULFONATE;NSC221196;WLN: WS1&O-SN-4&4&4;NSC-221196;NS00121714;H11513

Chemical Property of Stannane, tributyl[(methylsulfonyl)oxy]-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 51.75000
• Density: g/cm³
• LogP: 5.38920
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 11
• Exact Mass: 386.093769
• Heavy Atom Count: 18
• Complexity: 274

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): A poison. TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
• Hazard Codes: A poison. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)OS(=O)(=O)C

Technology Process of Stannane, tributyl[(methylsulfonyl)oxy]-

There total 2 articles about Stannane, tributyl[(methylsulfonyl)oxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tributyltin chloride (1461-22-9) + silver methanesulfonate (2386-52-9) → (C4H9)3SnOSO2CH3 (13302-06-2)

Guidance literature:

In dichloromethane; to ClSnBu3 in CH2Cl2 is added AgSO3Me, mixt. is stirred at room temp. for 1 h; filtration, solvent is removed under reduced pressure, residue is heated at 0.01 mmHg, elem. anal.;

DOI:10.1016/0022-328X(92)83182-H

Reference yield:

methanesulfonic acid (75-75-2,98527-29-8) + bis(tri-n-butyltin)oxide (56-35-9) → (C4H9)3SnOSO2CH3 (13302-06-2)

Guidance literature:

In toluene; 1:2; azeotropic dehydration; boiling for 2-4 h; removal of solvent;

upstream raw materials:

methanesulfonic acid

bis(tri-n-butyltin)oxide

tributyltin chloride

silver methanesulfonate

Refernces