Technology Process of 1-Methoxy-3-(methylsulfonyl)-2-nitrobenzene
There total 5 articles about 1-Methoxy-3-(methylsulfonyl)-2-nitrobenzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
Ambient temperature;
DOI:10.1021/jm00063a014
- Guidance literature:
-
Multi-step reaction with 5 steps
1: SOCl2
2: 1.) NaN3, 2.) H2O, 4.) NaOH, 5.) HCl
3: 1.) 98percent sulfuric acid, NaNO2, 2.) CuCl2, 36percent aq. HCl / 1.) acetic acid, 10 deg C, 1 h, 2.) acetic acid, RT, 1 h
4: 35 percent / dimethylformamide; H2O / 2 h / 100 °C
5: 61 percent / mcpba / CH2Cl2 / Ambient temperature
With
hydrogenchloride; sodium hydroxide; thionyl chloride; sodium azide; sulfuric acid; water; 3-chloro-benzenecarboperoxoic acid; copper dichloride; sodium nitrite;
In
dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jm00063a014
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 35 percent / dimethylformamide; H2O / 2 h / 100 °C
2: 61 percent / mcpba / CH2Cl2 / Ambient temperature
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jm00063a014