(Z)-1,2-Bis(phenylsulfonyl)ethene

Base Information

• Chemical Name: (Z)-1,2-Bis(phenylsulfonyl)ethene
• CAS No.: 963-15-5
• Molecular Formula: C14H12 O4 S2
• Molecular Weight: 308.379
• Hs Code.: 2904100000
• European Community (EC) Number: 635-447-6
• NSC Number: 202472
• DSSTox Substance ID: DTXSID201020293
• Nikkaji Number: J181.735C
• Mol file: 963-15-5.mol

Synonyms:(Z)-1,2-Bis(phenylsulfonyl)ethene;963-15-5;cis-1,2-Bis(phenylsulfonyl)ethylene;[(Z)-2-(benzenesulfonyl)ethenyl]sulfonylbenzene;(Z)-1-(2-(phenylsulfonyl)vinylsulfonyl)benzene;CIS-1,2-DI(PHENYLSULFONYL)ETHYLENE;SCHEMBL2787588;DTXSID201020293;MFCD00010140;NSC202472;(z)-1,2-bis(phenylsulfonyl)ethylene;AKOS024258199;cis-1,2-Bis-(phenylsulfonyl)ethylene;NSC-202472;AS-61376;B1573;CS-0112890;[(1Z)-2-(benzenesulfonyl)ethenesulfonyl]benzene;A847761;CIS-1,2-BIS(PHENYLSULFONYL)ETHYLENE 98+%

Chemical Property of (Z)-1,2-Bis(phenylsulfonyl)ethene

Chemical Property:

• Melting Point: 85-87 °C(lit.)
• Boiling Point: 545°Cat760mmHg
• Flash Point: 363.3°C
• PSA: 85.04000
• Density: 1.355g/cm³
• LogP: 4.56700
• Storage Temp.: Store below +30°C.
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 308.01770121
• Heavy Atom Count: 20
• Complexity: 473

Purity/Quality:

98% ^*data from raw suppliers

(Z)-1,2-Bis(phenylsulfonyl)ethene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)S(=O)(=O)C=CS(=O)(=O)C2=CC=CC=C2
• Isomeric SMILES: C1=CC=C(C=C1)S(=O)(=O)/C=C\S(=O)(=O)C2=CC=CC=C2

Technology Process of (Z)-1,2-Bis(phenylsulfonyl)ethene

There total 3 articles about (Z)-1,2-Bis(phenylsulfonyl)ethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

cis-1,2-bis-phenylsulfanyl-ethylene (18893-62-4) → (Z)-1,2-bis(phenylsulfonyl)ethene (963-15-5)

Guidance literature:

With dihydrogen peroxide; In acetic acid; for 2h; Heating;

DOI:10.1080/00397919608003606

Reference yield:

potassium thiophenolate (3111-52-2) → (Z)-1,2-bis(phenylsulfonyl)ethene (963-15-5)

Guidance literature:

Multi-step reaction with 2 steps

1: ethanolic KOH

2: aqueous hydrogen peroxide; acetic acid

With potassium hydroxide; dihydrogen peroxide; acetic acid;

DOI:10.1021/ja01651a036

Reference yield:

→ (Z)-1,2-bis(phenylsulfonyl)ethene (963-15-5)

Guidance literature:

upstream raw materials:

cis-1,2-bis-phenylsulfanyl-ethylene

potassium thiophenolate

Downstream raw materials:

(+/-)-trans-2,3-bis(phenylsulfonyl)-7-oxabicyclo[2.2.1]hept-5-ene

1-(Phenylsulfonyl)pyrrolo<1',2':3,4>pyrimido<2,1,6-cd>pyrrolizin

1-(6-Phenylsulfonyl-3H-pyrrolizin-5-yl)-2-pyrrolcarbaldehyd

1-<6-(Phenylsulfonyl)-3-(pyrrol-2-ylmethylen)pyrrolizin-5-yl>-2-pyrrolcarbaldehyd

Refernces

• 1、 Cossu, Sergio,De Lucchi, Ottorino,Durr, Richard,Fabris, Fabrizio. "An alternative, inexpensive preparation of phenylsulfonylethylene". . p. 211 - 216. Retrieved 2007/10/03.