d-Tetramethrin

Base Information

• Chemical Name: d-Tetramethrin
• CAS No.: 1166-46-7
• Molecular Formula: C₁₉H₂₅NO₄
• Molecular Weight: 331.412
• European Community (EC) Number: 214-619-0
• ICSC Number: 0335
• UNII: 99PWN9P00O
• DSSTox Substance ID: DTXSID4058289
• Nikkaji Number: J203.426C
• Wikidata: Q27272231
• ChEMBL ID: CHEMBL1892154
• Mol file: 1166-46-7.mol

Synonyms:1166-46-7;d-Tetramethrin;D-trans-Tetramethrin;(+)-trans-Tetramethrin;(1R)-trans-Tetramethrin;(+)-trans-Phthalthrin;Tetramethrin, D-trans-;trans-Tetramethrin;(1,3,4,5,6,7-Hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl (1R-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate;dl-trans-Phthalthrin;EINECS 214-619-0;(1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;Tetramethrin, ( )-trans-;Tetramethrin, (+)-trans-;UNII-99PWN9P00O;99PWN9P00O;5284-41-3;Multicide;Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-, ester with N-(hydroxymethyl)-1-cyclohexene-1,2-dicarboximide, (+)-(E)-;NSC 190939;(1,3,4,5,6,7-Hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl (1R-trans)-2,2-dimethyl-3-(2-methylprop-1-e;(1,3,4,5,6,7-Hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl trans-(+-)-2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate;(1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1R,3S)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;52556-74-8;Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl ester, trans-(+-)-;BIOTETRAMETHRIN;( )-trans-Tetramethrin;1R-TRANS-TETRAMETHRIN;SCHEMBL2973441;Tetramethrin [ANSI:BSI:ISO];CHEMBL1892154;DTXSID4058289;Tetramethrin [(1R)-trans isomer];(1-Cyclohexene-1,2-dicarboximido)methyl-2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate;2,2-Dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid, ester with N-(hydroxymethyl)-1-cyclohexene-1,2-dicarboximide or 1-cyclohexene-1,2-dicarboximidomethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate;AKOS024259100;NCGC00163748-01;NCGC00163748-02;NCGC00163748-03;LS-58694;LS-58700;Cyclohexene-1,2-dicarboximido)methyl 2,2-dimethyl-;d-trans-Tetramethrin 100 microg/mL in Acetonitrile;W-108578;Q27272231;(1,3-dioxo-1,3,4,5,6,7-hexahydro-2H-isoindol-2-yl)methyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropane-1-carboxylate;(1,3-dioxo-1,3,4,5,6,7-hexahydro-2H-isoindol-2-yl)methyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropanecarboxylate;(1,3-dioxo-2,3,4,5,6,7-hexahydro-1H-isoindol-2-yl)methyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyclopropane-1-carboxylate;(1R)-2,2-Dimethyl-3alpha-(2-methyl-1-propenyl)cyclopropanecarboxylic acid (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl ester;(1R,3R)-(1,3-dioxo-4,5,6,7-tetrahydro-1H-isoindol-2(3H)-yl)methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate;(1R,3R)-2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl ester;CYCLOPROPANECARBOXYLIC ACID, 2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)-,(1,3,4,5,6,7-HEXAHYDRO-1,3-DIOXO-2H-ISOINDOL-2-YL)METHYL ESTER, (1R,3R)-

Chemical Property of d-Tetramethrin

Chemical Property:

• Melting Point: 68-70oC
• Boiling Point: 453.228 °C at 760 mmHg
• PKA: -2.55±0.20(Predicted)
• Flash Point: 227.905 °C
• PSA: 63.68000
• Density: 1.2 g/cm³
• LogP: 2.90280
• Water Solubility.: insoluble
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 331.17835828
• Heavy Atom Count: 24
• Complexity: 639

Purity/Quality:

99% ^*data from raw suppliers

Rich-D-T-tetramethrin TC 95 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CC1C(C1(C)C)C(=O)OCN2C(=O)C3=C(C2=O)CCCC3)C
• Isomeric SMILES: CC(=C[C@@H]1[C@H](C1(C)C)C(=O)OCN2C(=O)C3=C(C2=O)CCCC3)C
• Inhalation Risk: No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.
• Effects of Short Term Exposure: The substance is irritating to the eyes and skin.

Technology Process of d-Tetramethrin

There total 3 articles about d-Tetramethrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ tetramethrin (1166-46-7,1166-47-8,1166-48-9,5284-41-3,51348-90-4,51348-91-5,52556-74-8,74430-90-3,7696-12-0)

Guidance literature:

DOI:10.1007/BF00762571

Reference yield:

→ (+)-trans-tetramethrin (1166-46-7,1166-47-8,1166-48-9,5284-41-3,51348-90-4,51348-91-5,52556-74-8,74430-90-3,7696-12-0)

Guidance literature:

N-Hydroxymethyl-tetrahydro-phthalimid, dl-trans-Chrysanthemsaeure-chlorid;

Reference yield:

→ cis-Tetramethrin (1166-46-7,1166-47-8,1166-48-9,5284-41-3,7696-12-0,51348-90-4,51348-91-5,52556-74-8,74430-90-3)

Guidance literature:

N-Hydroxymethyl-tetrahydro-phthalimid, dl-cis-Chrysanthemsaeure-chlorid;

Refernces

• 1、 -. "Methods and agents for combating cockroaches". . . Retrieved 2008/06/13.