9-Phenyl-9H,9'H-[3,3']bicarbazolyl

Base Information

• Chemical Name: 9-Phenyl-9H,9'H-[3,3']bicarbazolyl
• CAS No.: 1060735-14-9
• Molecular Formula: C30H20N2
• Molecular Weight: 408.502
• Hs Code.: 2933998090
• Mol file: 1060735-14-9.mol

Synonyms:.3-(9-phenyl-9H-carbazol-3-yl)-9H-carbazole;9-PHENYL-9H,9'H-[3,3']BICARBAZOLYL;.PCC;9-phenyl-9H,9'H-3,3'-bicarbazole;.9-phenyl-9H,9'H-[3,3']bicarbazolyl;.9-phenyl-3,3'-bi(9H-carbazol);.9-phenyl-3,3'-bi(9H-carbazole);

Chemical Property of 9-Phenyl-9H,9'H-[3,3']bicarbazolyl

Chemical Property:

• Boiling Point: 685.6±37.0 °C(Predicted)
• PKA: 17.10±0.30(Predicted)
• PSA: 20.72000
• Density: 1.23±0.1 g/cm3(Predicted)
• LogP: 8.08520
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

9-Phenyl-9H,9''H-3,3''-bicarbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-Phenyl-9H,9'H-[3,3']bicarbazolyl

There total 18 articles about 9-Phenyl-9H,9'H-[3,3']bicarbazolyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

N-phenyl-9H-carbazol-3-boronic acid (854952-58-2) + 3-bromo-9H-carbazole (1592-95-6) → 9-phenyl-3,3'-bicarbazole (1060735-14-9)

Guidance literature:

N-phenyl-9H-carbazol-3-boronic acid; 3-bromo-9H-carbazole; With potassium carbonate; In ethanol; water; toluene; for 0.5h; Inert atmosphere;

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenylphosphine; In ethanol; water; toluene; for 2h; Reflux;

Reference yield: 90.0%

3-bromo-9-phenyl-9H-carbazole (1153-85-1) + (9H-carbazol-3-yl)boronic acid (851524-97-5) → 9-phenyl-3,3'-bicarbazole (1060735-14-9)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In water; toluene; for 12h; Reflux;

Reference yield: 87.0%

3-bromo-9H-carbazole (1592-95-6) + 9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole (1126522-69-7) → 9-phenyl-3,3'-bicarbazole (1060735-14-9)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In water; toluene; for 5h; Inert atmosphere; Reflux;

upstream raw materials:

N-phenyl-9H-carbazol-3-boronic acid

3-bromo-9H-carbazole

9H-carbazole

bromobenzene

Downstream raw materials:

9-phenyl-9'-[4-(10-phenyl-9-anthryl)phenyl]-3,3'-bi(9H-carbazole)

N-phenylcarbazole

9-(dibenzo[b,d]thiophen-2-yl)-9'-phenyl-9H,9'H-3,3'-bicarbazole

9-(dibenzo[b,d]thiophen-4-yl)-9?-phenyl-9H,9'H-3,3?-bicarbazole

Refernces

• 1、 Lv, Xialei,Wang, Bo,Tan, Jianghong,Huang, Zhi,Zhang, Qing,Xiang, Songpo,Liu, Wei,Zhuang, Shaoqing,Wang, Lei. "Constructing diazacarbazole-bicarbazole bipolar hybrids by optimizing the linker group for high efficiency, low roll off electrophosphorescent devices". . p. 54 - 62. Retrieved 2017.
• 2、 Chang, Chih-Hao,Kuo, Ming-Cheng,Lin, Wei-Chieh,Chen, Yu-Ting,Wong, Ken-Tsung,Chou, Shu-Hua,Mondal, Ejabul,Kwong, Raymond C.,Xia, Sean,Nakagawa, Tetsuya,Adachi, Chihaya. "A dicarbazole-triazine hybrid bipolar host material for highly efficient green phosphorescent OLEDs". . p. 3832 - 3838. Retrieved 2012.
• 3、 -. "Boron-nitrogen heteropolyaromatic ring compound and application thereof". Paragraph 0149-0153. . Retrieved 2020/08/29.
• 4、 -. "Novel compound and organic light emitting device comprising the same". Paragraph 0200-0203. . Retrieved 2020/03/05.