Oxygen O-17

Base Information

• Chemical Name: Oxygen O-17
• CAS No.: 67321-81-7
• Molecular Formula: O2
• Molecular Weight: 34
• European Community (EC) Number: 687-306-3
• UNII: 541C150APR
• DSSTox Substance ID: DTXSID80436580
• Wikidata: Q27261150
• Mol file: 67321-81-7.mol

Synonyms:Oxygen O-17;Oxygen, mol. (17O2);67321-81-7;541C150APR;UNII-541C150APR;Oxygen-17O2;OXYGEN (O17O17);DTXSID80436580;Oxygen-17O2, 10 atom % 17O;Oxygen-17O2, 20 atom % 17O;Oxygen-17O2, 40 atom % 17O;Oxygen-17O2, 45 atom % 17O;Oxygen-17O2, 50 atom % 17O;Oxygen-17O2, 60 atom % 17O;Oxygen-17O2, 70 atom % 17O;Oxygen-17O2, 80 atom % 17O;Oxygen-17O2, 85 atom % 17O;Oxygen-17O2, 90 atom % 17O;Q27261150

Chemical Property of Oxygen O-17

Chemical Property:

• PSA: 34.14000
• LogP: 0.06700
• XLogP3: -1.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 33.99826351
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

OXYGEN-17O2 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: O
• Statements: 8
• Safety Statements: 17

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O=O
• Isomeric SMILES: [17O]=[17O]

Technology Process of Oxygen O-17

There total 3 articles about Oxygen O-17 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

xenon difluoride (13709-36-9) + 17O-water (13968-48-4) → dioxygen-(17)O (67321-81-7)

Guidance literature:

In neat (no solvent, gas phase); byproducts: Xe, HF; at 50°C for 3 h; fractional distn. at low temp.;

DOI:10.1134/S0036023611030053

Reference yield:

18O-labeled water (14797-71-8) → dioxygen-(17)O (67321-81-7) + oxygen-18 (32767-18-3)

Guidance literature:

With tetrabutylammonium hexafluorophosphate; In acetonitrile; Electrolysis;

DOI:10.1021/acs.inorgchem.5b00398

Reference yield:

17O-water (13968-48-4) → dioxygen-(17)O (67321-81-7)

Guidance literature:

In neat (no solvent); Electrochem. Process; in the course of electrolysis;

DOI:10.1134/S0036023611030053

upstream raw materials:

¹⁷O-water

xenon difluoride

¹⁸O-labeled water

Downstream raw materials:

Cp(CO)2Re[η2-O=C(p-CF3C6H4)(2-C(17)OC6H4COMe)]

Cp(CO)2Re[η2-O=C(p-CF3C6H4)(2-COC6H4C(17)OMe)]

Bi₀₉₁₃V_0.087⁽¹⁷⁾O_1.587

Bi₀₈₅₂V_0.148⁽¹⁷⁾O_1.648

Refernces

• 1、 Artyukhov,Kravets,Artyukhov,Babichev,Ryzhkov. "Synthesis of water and molecular oxygen highly enriched in 17O and 18O isotopes from carbon oxides". . p. 335 - 337. Retrieved 2011/08/22.