6-Azoniaspiro(5.5)undecane bromide

Base Information

• Chemical Name: 6-Azoniaspiro(5.5)undecane bromide
• CAS No.: 6286-82-4
• Molecular Formula: C10H20BrN
• Molecular Weight: 234.179
• European Community (EC) Number: 613-093-3
• NSC Number: 10398
• DSSTox Substance ID: DTXSID00978593
• Mol file: 6286-82-4.mol

Synonyms:6286-82-4;6-Azoniaspiro(5.5)undecane bromide;1,1'-Spirobipiperidinium bromide;6-Azaspiro[5.5]undecan-6-ium bromide;6-AZONIASPIRO(5,5)UNDECANE BROMIDE;6-Azaspiro(5,5)undecane bromide;6-azoniaspiro[5.5]undecane;bromide;NSC 10398;6-Azoniaspiro[5.5]undecane bromide;6-Azoniaspiro[5.5]undecane, bromide;C10H20N.Br;6-lambda-5-azaspiro[5.5]undecan-6-ylium bromide;C10-H20-N.Br;SCHEMBL21381968;DTXSID00978593;NSC10398;NSC-10398;WLN: T6KTJ A-& AT6KTJ &E;AKOS026669176;6-azoniaspiro-[5.5]-undecane bromide;GS-2509;LS-23551;6lambda5-azaspiro[5.5]undecan-6-ylium bromide

Chemical Property of 6-Azoniaspiro(5.5)undecane bromide

Chemical Property:

• Melting Point: 310 °C(Solv: isopropanol (67-63-0))
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -0.86620
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 233.07791
• Heavy Atom Count: 12
• Complexity: 99.3

Purity/Quality:

98%min ^*data from raw suppliers

6-Lambda-5-azaspiro[5.5]undecan-6-ylium bromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC[N+]2(CC1)CCCCC2.[Br-]

Technology Process of 6-Azoniaspiro(5.5)undecane bromide

There total 5 articles about 6-Azoniaspiro(5.5)undecane bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

piperidine (110-89-4) + 1,5-dibromo-pentane (111-24-0) → 6-azaspiro[5.5]undecan-6-ium bromide (6286-82-4)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In chloroform; for 15h; Reflux;

Reference yield: 99.0%

1-(5-bromopentyl)piperidine → 6-azaspiro[5.5]undecan-6-ium bromide (6286-82-4)

Guidance literature:

In acetonitrile; at 60 - 65 ℃; for 16h;

Reference yield:

1,5-dibromo-pentane (111-24-0) → 6-azaspiro[5.5]undecan-6-ium bromide (6286-82-4)

Guidance literature:

With ammonia; Behandeln des Reaktionsprodukts mit wss. Bromwasserstoffsaeure;

upstream raw materials:

piperidine

1,5-dibromo-pentane

Downstream raw materials:

piperidine

Refernces

• 1、 Chen, Nanjun,Fan, Jiantao,Hu, Chuan,Jin, Yiqi,Lee, Young Moo,Li, Hui,Liu, Haijun,Wu, Bo,Xu, Shaoyi. "Insight into the Alkaline Stability of N-Heterocyclic Ammonium Groups for Anion-Exchange Polyelectrolytes". supporting information. p. 19272 - 19280. Retrieved 2021/07/25.
• 2、 -. "Preparation method of fluorozirconate". . . Retrieved 2017/12/01.