Undecafluoro(heptafluoropropyl)cyclohexane

Base Information

• Chemical Name: Undecafluoro(heptafluoropropyl)cyclohexane
• CAS No.: 374-59-4
• Molecular Formula: C9F18
• Molecular Weight: 450.07
• DSSTox Substance ID: DTXSID50515856
• Nikkaji Number: J190.763H
• Wikidata: Q82376965
• Mol file: 374-59-4.mol

Synonyms:374-59-4;Undecafluoro(heptafluoropropyl)cyclohexane;PERFLUORO(PROPYLCYCLOHEXANE);(Heptafluoropropyl)undecafluorocyclohexane;1,1,2,2,3,3,4,4,5,5,6-UNDECAFLUORO-6-(1,1,2,2,3,3,3-HEPTAFLUOROPROPYL)CYCLOHEXANE;Perfluoro-n-propylcyclohexane;perfluoro(propyl-cyclohexane);SCHEMBL7051335;DTXSID50515856;ITPKQVFBLQIXLT-UHFFFAOYSA-N;MFCD20526344;NS00110552;Perfluoro-n-propylcyclohexane, 55% Remainder other perfluorocarbons

Chemical Property of Undecafluoro(heptafluoropropyl)cyclohexane

Chemical Property:

• Vapor Pressure: 23.607mmHg at 25°C
• Boiling Point: 114.414°C at 760 mmHg
• Flash Point: 33.968°C
• Density: 1.772g/cm³
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 18
• Rotatable Bond Count: 2
• Exact Mass: 449.9712569
• Heavy Atom Count: 27
• Complexity: 577

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(C(C(C(C(C1(F)F)(F)F)(F)F)(F)F)(F)F)(C(C(C(F)(F)F)(F)F)(F)F)F

Technology Process of Undecafluoro(heptafluoropropyl)cyclohexane

There total 13 articles about Undecafluoro(heptafluoropropyl)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(1Z)-Pentafluoroprop-1-enylcyclohexane (291751-93-4) → perfluoro(1-cyclohexylpropane) (374-59-4)

Guidance literature:

With cobalt (III) fluoride; at 375 ℃;

DOI:10.1039/a909777e

Reference yield: 63.0%

(1,1,2,3,3,3-Hexafluoropropyl)cyclohexane (53005-30-4) → perfluoro(1-cyclohexylpropane) (374-59-4)

Guidance literature:

With cobalt (III) fluoride; at 375 ℃;

DOI:10.1039/a909777e

Reference yield: 51.0%

2-(1,2,3,3,4,4,5,5,6,6-decafluorocyclohexy)oxolane → perfluoro(1-cyclohexylpropane) (374-59-4) + perfluoro-2-cyclohexyloxolane

Guidance literature:

With calcium fluoride; cobalt (III) fluoride; at 440 ℃; in nickel tube;

DOI:10.1016/S0022-1139(00)82331-3

upstream raw materials:

propylcyclohexane

N-methyldecahydroquinoline

N-methyl-1,2,3,4-tetrahydroquinoline

3-cyclohexyl-2-methyl-propionic acid methyl ester

Refernces

• 1、 Lin, Wen-Huey,Lagow, Richard J.. "THE SYNTHESIS OF HIGHLY FLUORINATED ALKYLCYCLOHEXANES FOR USE AS OXYGEN CARRIERS AND THE 19F AND 13C NMR SPECTRA OF ALKYLCYCLOHEXANES". . p. 345 - 358. Retrieved 2007/10/02.