3,3,4,4-Tetrafluoro-1,6-diiodohexane

Base Information

• Chemical Name: 3,3,4,4-Tetrafluoro-1,6-diiodohexane
• CAS No.: 2163-06-6
• Molecular Formula: C6H8F4I2
• Molecular Weight: 409.932
• Hs Code.: 2903799090
• European Community (EC) Number: 832-005-6
• DSSTox Substance ID: DTXSID90382165
• Nikkaji Number: J908.011B
• Wikidata: Q82173485
• Mol file: 2163-06-6.mol

Synonyms:1,6-Diiodo-3,3,4,4-tetrafluorohexane;2163-06-6;3,3,4,4-tetrafluoro-1,6-diiodohexane;1,2-BIS(2-IODOETHYL)TETRAFLUOROETHANE;SCHEMBL52183;DTXSID90382165;JFYZKVSETQEPKR-UHFFFAOYSA-N;MFCD00153068;AKOS007930474;MS-20263;Hexane, 3,3,4,4-tetrafluoro-1,6-diiodo-;1,2-BIS(2-AMINOPHENOXY)ETHANE-N,N,N,N-TETRAACETICACIDTETRAPOTASSIUMSALT

Chemical Property of 3,3,4,4-Tetrafluoro-1,6-diiodohexane

Chemical Property:

• Melting Point: 114°C
• PSA: 0.00000
• LogP: 3.90720
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 409.86516
• Heavy Atom Count: 12
• Complexity: 122

Purity/Quality:

99% ^*data from raw suppliers

1,6-Diiodo-3,3,4,4-tetrafluorohexane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CI)C(C(CCI)(F)F)(F)F

Technology Process of 3,3,4,4-Tetrafluoro-1,6-diiodohexane

There total 3 articles about 3,3,4,4-Tetrafluoro-1,6-diiodohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

ethene (74-85-1) + 1,2-diiodotetrafluoroethane (354-65-4) → 3,3,4,4-tetrafluoro-1,6-diiodo-hexane (2163-06-6)

Guidance literature:

copper(l) iodide; In acetonitrile; at 160 ℃; for 14h; Product distribution; other catalyst; also in the presence of radical initiator; different reaction conditions;

DOI:10.1016/0022-1139(95)03231-2

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + 1,2-diiodotetrafluoroethane (354-65-4) → 3,3,4,4-tetrafluoro-1,6-diiodo-hexane (2163-06-6)

Guidance literature:

In diethyl ether;

DOI:10.1007/BF00845703

Reference yield:

→ 3,3,4,4-tetrafluoro-1,6-diiodo-hexane (2163-06-6)

Guidance literature:

upstream raw materials:

diazomethane

1,2-diiodotetrafluoroethane

ethene

Downstream raw materials:

1-(1,1,2,2-tetrafluoro-3-buten-1-yl)-2,2,3,3-tetraflouoro-cyclobutane

3-(3,4-Dibromo-1,1,2,2-tetrafluoro-butyl)-1,1,2,2-tetrafluoro-cyclobutane

1,1,2,2-Tetrafluoro-3-(1,1,2,2-tetrafluoro-butyl)-cyclobutane

3,3,4,4-Tetrafluoro-1,5-hexadiene

Refernces

• 1、 Manseri, A.,Ameduri, B.,Boutevin, B.,Kotora, M.,Hajek, M.,Caporiccio, G.. "Synthesis of telechelic dienes from fluorinated α,ω-diiodoalkanes. Part I. Divinyl and diallyl derivatives from model I(C2F4)nI compounds". . p. 151 - 158. Retrieved 2007/10/02.