6-BROMO-1-AMINOPYRENE

Base Information

• Chemical Name: 6-BROMO-1-AMINOPYRENE
• CAS No.: 42882-08-6
• Molecular Formula: C16H10BrN
• Molecular Weight: 296.166
• Hs Code.: 2921499090
• Mol file: 42882-08-6.mol

Synonyms:6-BROMO-1-AMINOPYRENE

Chemical Property of 6-BROMO-1-AMINOPYRENE

Chemical Property:

• Boiling Point: 488.0±20.0 °C(Predicted)
• PKA: 4.04±0.30(Predicted)
• PSA: 26.02000
• Density: 1.641±0.06 g/cm3(Predicted)
• LogP: 5.50990

Purity/Quality:

6-BROMO-1-AMINOPYRENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 6-BROMO-1-AMINOPYRENE

There total 4 articles about 6-BROMO-1-AMINOPYRENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.6%

C16H8BrN3 → 1-amino-6-bromopyrene (42882-08-6)

Guidance literature:

With sodium hydrogen sulfide monohydrate; In tetrahydrofuran; water; for 3h; Reflux;

DOI:10.1039/d0cc07429b

Reference yield: 26.0%

pyrene (129-00-0) → 1-amino-6-bromopyrene (42882-08-6)

Guidance literature:

pyrene; With hydrogen bromide; dihydrogen peroxide; In methanol; diethyl ether; at 20 ℃; for 16h; Inert atmosphere;

With nitric acid; acetic acid; In methanol; diethyl ether; at 20 ℃; for 2h; Inert atmosphere;

With zinc; In methanol; diethyl ether; at 90 ℃; for 72h; Inert atmosphere;

DOI:10.1002/chem.201605846

Reference yield:

1-bromo-6-nitropyrene (42882-03-1) → 1-amino-6-bromopyrene (42882-08-6)

Guidance literature:

With hydrazine hydrate; nickel;

upstream raw materials:

1-bromo-6-nitropyrene

pyrene

1,6-dibromopyrene

Downstream raw materials:

C₃₇H₂₃N

C₃₈H₂₃N₃

C₃₅H₂₂N₄

C₃₇H₂₂F₂N₂

Refernces

• 1、 Ludwanowski, Simon,Hoenders, Daniel,Kalayci, Kubra,Frisch, Hendrik,Barner-Kowollik, Christopher,Walther, Andreas. "Modular functionalization and hydrogel formation: via red-shifted and self-reporting [2+2] cycloadditions". . p. 805 - 808. Retrieved 2021.