Etrimfos

Base Information

• Chemical Name: Etrimfos
• CAS No.: 38260-54-7
• Molecular Formula: C10H17 N2 O4 P S
• Molecular Weight: 292.296
• Hs Code.: 2933599011
• European Community (EC) Number: 253-855-9
• UNII: XHX5LWR4ME
• DSSTox Substance ID: DTXSID7041964
• Nikkaji Number: J3.502E
• Wikidata: Q22807519
• Metabolomics Workbench ID: 45096
• ChEMBL ID: CHEMBL1316772
• Mol file: 38260-54-7.mol

Synonyms:Ekamet;ENT 29126;etrimfos;SAN 197

Chemical Property of Etrimfos

Chemical Property:

• Vapor Pressure: 7.74E-05mmHg at 25°C
• Melting Point: -3.35℃
• Refractive Index: nD20 1.5068
• Boiling Point: 352.6°Cat760mmHg
• PKA: -0.67±0.32(Predicted)
• Flash Point: 167°C
• PSA: 104.60000
• Density: 1.246g/cm³
• LogP: 2.98440
• Storage Temp.: APPROX 4°C
• Solubility.: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
• Water Solubility.: 40 mg l-1 (23-24 °C)
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 7
• Exact Mass: 292.06466520
• Heavy Atom Count: 18
• Complexity: 287

Purity/Quality:

98%Min ^*data from raw suppliers

Satisfar ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,N
• Statements: 22-50/53
• Safety Statements: 60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Organophosphate Insecticides
• Canonical SMILES: CCC1=NC(=CC(=N1)OP(=S)(OC)OC)OCC
• Description: Etrimfos is a colorless liquid, mp ?3.35 ?C, vp 6.5 mPa (20 ?C). Solubility in water is 40 mg/L (23–24 ?C). It is miscible with most organic solvents. Log Kow > 3.3. Neat etrimfos is unstable and degrades ca. 40% in 28 d at 50 ?C, but the dilute solutions in nonpolar solvents and its formulations are stable (about 5% loss in 1 y at ca. 20 ?C). It is hydrolyzed in aqueous media; DT50 (25 ?C) at pH 3, 6, and 9 are 0.4, 16, and 14 d, respectively.
• Uses: Satisfar is a pesticide sprayed on plants and vegetables as insecticide to fend off pests. Agricultural insecticide. Etrimfos is used to control chewing insects in top fruit, vines, olives and a number of other crops. It is also used to control stem borers in rice and insect and acarid pests of stored products.

Technology Process of Etrimfos

There total 2 articles about Etrimfos which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.1%

C8H11N2O2(1-)*Na(1+) (1445137-34-7) + dimethyl chlorothiophosphate (2524-03-0) → etrimfos (38260-54-7)

Guidance literature:

With dmap; N-benzyl-N,N,N-triethylammonium chloride; sodium dodecyl sulfate; potassium carbonate; In water; at 50 ℃; for 2.5h; pH=9.5 - 10;

DOI:10.1080/10426507.2012.702824

Reference yield:

→ etrimfos (38260-54-7)

Guidance literature:

upstream raw materials:

C₈H₁₁N₂O₂^(1-)*Na⁽¹⁺⁾

dimethyl chlorothiophosphate

Refernces

• 1、 -. "Insecticidal composition for agricultural and horticultural use". . . Retrieved 2008/06/13.