9-(biphenyl-4-yl)-3-boric acid-9H-carbazole

Base Information

• Chemical Name: 9-(biphenyl-4-yl)-3-boric acid-9H-carbazole
• CAS No.: 1028648-22-7
• Molecular Formula: C24H18BNO2
• Molecular Weight: 363.223
• Mol file: 1028648-22-7.mol

Synonyms:9-(biphenyl-4-yl)-3-boric acid-9H-carbazole;(9-([1,1'-biphenyl]-4-yl)-9H-carbazol- 3-yl)boronic acid;(9-([1,1'-biphenyl]4-yl)-9H-carbazol-3yl)boronic;9-(Biphenyl-4-yl)-9H-carbazol-3-yl)-boronic acid

Chemical Property of 9-(biphenyl-4-yl)-3-boric acid-9H-carbazole

Chemical Property:

• Boiling Point: 555.9±60.0 °C(Predicted)
• PKA: 8.81±0.30(Predicted)
• PSA: 45.39000
• Density: 1.18±0.1 g/cm3(Predicted)
• LogP: 4.13050

Purity/Quality:

98%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-(biphenyl-4-yl)-3-boric acid-9H-carbazole

There total 11 articles about 9-(biphenyl-4-yl)-3-boric acid-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

9-[1,1′-biphenyl-4-yl]-3-bromo-9H-carbazole (894791-46-9) + Trimethyl borate (121-43-7,63156-11-6) → 9‐{[1,1'‐biphenyl]‐4‐yl}carbazol‐3‐ylboronic acid (1028648-22-7)

Guidance literature:

9-[1,1′-biphenyl-4-yl]-3-bromo-9H-carbazole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2h;

Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 20h;

With hydrogenchloride; water; In tetrahydrofuran; hexane; at 20 ℃; for 3h;

Reference yield: 86.0%

→ 9‐{[1,1'‐biphenyl]‐4‐yl}carbazol‐3‐ylboronic acid (1028648-22-7)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 3h;

at 20 ℃;

With hydrogenchloride; In water;

Reference yield:

9-[1,1′-biphenyl-4-yl]-3-bromo-9H-carbazole (894791-46-9) + boric acid tributyl ester (688-74-4) → 9‐{[1,1'‐biphenyl]‐4‐yl}carbazol‐3‐ylboronic acid (1028648-22-7)

Guidance literature:

9-[1,1′-biphenyl-4-yl]-3-bromo-9H-carbazole; With n-butyllithium; In tetrahydrofuran; at -90 ℃; for 1h; Inert atmosphere; Heating;

boric acid tributyl ester; In tetrahydrofuran; for 1h;

With hydrogenchloride; In tetrahydrofuran; water; Petroleum ether;

upstream raw materials:

9-[1,1′-biphenyl-4-yl]-3-bromo-9H-carbazole

Trimethyl borate

4-bromo-1,1'-biphenyl

9-([1,1’-biphenyl]-4-yl)-9H-carbazole

Downstream raw materials:

(4-(9-(biphenyl-4-yl)-9H-carbazol-3-yl)-phenyl)-biphenyl-4-yl-phenyl-amine

(4-(9-(biphenyl-4-yl)-9H-carbazol-3-yl)-phenyl)-(4-naphthalen-1-yl-phenyl)-biphenyl-4-yl-amine

(4-(9-biphenyl-4-yl-9H-carbazol-3-yl)-phenyl)-(4-naphthalen-1-yl-phenyl)-phenyl-amine

C₅₃H₃₅N₃

Refernces

• 1、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF". Paragraph 0134-0139; 0142. . Retrieved 2021/02/16.
• 2、 -. "ORGANIC LIGHT EMITTING DEVICE AND DISPLAY DEVICE HAVING THE SAME". Paragraph 0148; 0149. . Retrieved 2017/06/30.