2,3-dichlorooctane

Base Information

• Chemical Name: 2,3-dichlorooctane
• CAS No.: 21948-47-0
• Molecular Formula: C₈H₁₆Cl₂
• Molecular Weight: 183.121
• Hs Code.: 2903199000
• Mol file: 21948-47-0.mol

Synonyms:2,3-dichlorooctane

Chemical Property of 2,3-dichlorooctane

Chemical Property:

• Melting Point: -55.1°C
• Refractive Index: 1.4347 (estimate)
• Boiling Point: 221.51°C (estimate)
• PSA: 0.00000
• Density: 1.0333 (estimate)
• LogP: 3.80140

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,3-dichlorooctane

There total 8 articles about 2,3-dichlorooctane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

cis-2-octene (7642-04-8) → erythro 2,3-dichloroctane (21948-47-0,37464-71-4,75121-26-5)

Guidance literature:

With Phenylselenyl chloride; tetrabutyl-ammonium chloride; chlorine; In tetrachloromethane; acetonitrile; for 0.166667h; Heating;

DOI:10.1016/S0040-4039(01)91559-X

Reference yield: 84.0%

trans-2-Octene (13389-42-9) → erythro-2,3-dichlorooctane (21948-47-0,37464-71-4,75121-26-5)

Guidance literature:

With chloro-trimethyl-silane; benzyl(triethyl)ammoniumpermanganate; In dichloromethane; at 20 ℃;

DOI:10.1016/S0040-4039(97)00309-2

Reference yield: 82.0%

2-octene (111-67-1) → 2,3-dichloro-octane (21948-47-0)

Guidance literature:

With Amberlyst A-26 (iodide form); chlorine; In dichloromethane; for 2h; Ambient temperature;

DOI:10.1039/c39800001278

upstream raw materials:

2-octene

cis-2-octene

trans-2-Octene

(R)-(-)-2-iodooctane

Downstream raw materials:

cis-2-octene

Refernces

• 1、 Swamy, Peraka,Reddy, Marri Mahender,Kumar, Macharla Arun,Naresh, Mameda,Narender, Nama. "Vicinal dichlorination of olefins using NH4Cl and oxone ". . p. 251 - 257. Retrieved 2014/03/21.
• 2、 Marko, Istvan E.,Richardson, Paul R.,Bailey, Mark,Maguire, Anita R.,Coughlan, Niall. "Selective manganese-mediated transformations using the combination: KMnO4/Me3SiCl". . p. 2339 - 2342. Retrieved 2007/10/03.