tert-Butyl peroxypivalate

Base Information Edit

Chemical Name:tert-Butyl peroxypivalate
CAS No.:927-07-1
Deprecated CAS:928322-98-9,1935692-40-2
Molecular Formula:C9H18 O3
Molecular Weight:174.24
Hs Code.:2918300090
European Community (EC) Number:213-147-2
UN Number:3113
UNII:M0P448E3Y6
DSSTox Substance ID:DTXSID2027339
Nikkaji Number:J2.119I
Wikidata:Q72503996
Mol file:927-07-1.mol

Synonyms:tert-Butyl peroxypivalate;t-Butyl peroxypivalate;927-07-1;Lupersol 11;Esperox 31M;tert-Butyl perpivalate;Peroxypivalic acid, tert-butyl ester;Trigonox 25-C75;Trigonox 25/75;tert-butyl 2,2-dimethylpropaneperoxoate;tert-Butyl trimethylperoxyacetate;PROPANEPEROXOIC ACID, 2,2-DIMETHYL-, 1,1-DIMETHYLETHYL ESTER;EINECS 213-147-2;BRN 1704745;M0P448E3Y6;EC 213-147-2;4-02-00-00912 (Beilstein Handbook Reference);esperox31m;t-butyl perpivalate;tert.-butylperpivalat;SCHEMBL15165;UNII-M0P448E3Y6;TERT-BUTYLPEROXYPIVALATE;DTXSID2027339;peroxypivalic acid, t-butyl ester;BUTYL PEROXYPIVALATE, TERT-;PIVALOYL TERT-BUTYL PEROXIDE;NA2110;UN2110;AKOS006274845;TERT-BUTYL TERT-VALERYL PEROXIDE;LS-102487;TERT-BUTYL 2,2-DIMETHYLPEROXYPROPIONATE;2,2-Dimethyl-propaneperoxoic acid tert-butyl ester

Suppliers and Price of tert-Butyl peroxypivalate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 38 raw suppliers

Chemical Property of tert-Butyl peroxypivalate Edit

Chemical Property:

Appearance/Colour:colorless liquid free of foreign contaminant
Vapor Pressure:0.808mmHg at 25°C
Melting Point:-17 ºC
Refractive Index:1.410
Boiling Point:182.5 °C at 760 mmHg
Flash Point:53.5 °C
PSA：35.53000
Density:0.931 g/cm3
LogP:2.30580
Water Solubility.:insoluble
XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:174.125594432
Heavy Atom Count:12
Complexity:160
Transport DOT Label:Organic Peroxide

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s): (Solution) Flammable, dangerous fire risk. Oxidizing agent. May explode on heating.
Hazard Codes:(Solution) Flammable, dangerous fire risk. Oxidizing agent. May explode on heating.

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)C(=O)OOC(C)(C)C
Uses t-Butyl peroxypivalate is used as a polymerizationinitiator to make acrylic polymers.

Technology Process of tert-Butyl peroxypivalate

There total 3 articles about tert-Butyl peroxypivalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.7%

: 75-91-2
tert.-butylhydroperoxide

: 3282-30-2
pivaloyl chloride

: 927-07-1
tert-butyl peroxypivalate

Guidance literature:: With potassium hydroxide; In water; at 10 - 15 ℃;

Reference yield: 63.0%

: 75-91-2
tert.-butylhydroperoxide

: 75-98-9
Trimethylacetic acid

: 927-07-1
tert-butyl peroxypivalate

Guidance literature:: tert.-butylhydroperoxide; Trimethylacetic acid; With dmap; In dichloromethane; water; at 0 ℃; for 0.166667h; Inert atmosphere;

With dicyclohexyl-carbodiimide; In dichloromethane; water; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/asia.201800534