Chloromethylphenylsilane

Base Information

• Chemical Name: Chloromethylphenylsilane
• CAS No.: 1631-82-9
• Molecular Formula: C7H9 Cl Si
• Molecular Weight: 156.687
• Hs Code.: 2931900090
• European Community (EC) Number: 216-633-2
• UNII: 89VL1KZ19R
• DSSTox Substance ID: DTXSID801033222
• Mol file: 1631-82-9.mol

Synonyms:Chloromethylphenylsilane;Phenylmethylchlorosilane;1631-82-9;Silane, chloromethylphenyl-;Chloro(methyl)phenylsilane;chloro-methyl-phenylsilicon;methylphenylchlorosilane;89VL1KZ19R;(Chloromethylsilyl)benzene;UNII-89VL1KZ19R;Benzene,(chloromethylsilyl)-;SCHEMBL448267;SCHEMBL3315510;METHYLPHENYLSILYL CHLORIDE;CHLORO(PHENYL)METHYLSILANE;GVPNBWPLCHOFMX-UHFFFAOYSA-N;DTXSID801033222;Silane, chloro(methyl)(phenyl)-,;EINECS 216-633-2;MFCD00045146;AKOS024462714;(+/-)-CHLOROMETHYLPHENYLSILANE;FS-5660;FT-0623681;S13525;J-010015;Chloro(methyl)phenylsilane, technical, >=93.0% (GC)

Chemical Property of Chloromethylphenylsilane

Chemical Property:

• Melting Point: <0°C
• Refractive Index: n20/D 1.515(lit.)
• Boiling Point: 113 °C(lit.)
• Flash Point: 144 °F
• PSA: 0.00000
• Density: 1.043 g/mL at 25 °C(lit.)
• LogP: 1.48600
• Storage Temp.: Flammables area
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 155.0083795
• Heavy Atom Count: 9
• Complexity: 79

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chloro(methyl)phenylsilane technical, ≥93.0% (GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C
• Statements: 10-15-34-14
• Safety Statements: 26-28-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Si](C1=CC=CC=C1)Cl

Technology Process of Chloromethylphenylsilane

There total 15 articles about Chloromethylphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

methylphenylsilane (766-08-5,146088-00-8) → chloro(methyl)phenylsilane (1631-82-9)

Guidance literature:

With hydrogenchloride; In diethylene glycol dimethyl ether; at 60 ℃; for 1h; Time;

Reference yield: 91.0%

methylphenylsilane (766-08-5,146088-00-8) → chloro-methyl-silane (993-00-0) + chloro(methyl)phenylsilane (1631-82-9)

Guidance literature:

With hydrogenchloride; In diethyl ether; at 80 ℃; for 26h; Temperature; Solvent;

Reference yield: 42.0%

methylphenylsilane (766-08-5,146088-00-8) + dichloromethylphenylsilane (149-74-6) → chloro(methyl)phenylsilane (1631-82-9)

Guidance literature:

With tetrabutylammomium bromide; at 120 ℃; for 24h; Further Variations:; Temperatures; Equilibrium constant;

DOI:10.1080/10426509608046380

upstream raw materials:

Dichloromethylsilane

methylphenylsilane

chloro-methyl-silane

chlorobenzene

Downstream raw materials:

Si,Si'-dichloro-Si,Si'-dimethyl-Si,Si'-diphenyl-Si,Si'-ethane-1,2-diyl-bis-silane

allyl(methyl)(phenyl)silane

1-Methyl-1,2,2-triphenyl-disilane

methyl(pent-4-en-1-yl)(phenyl)silane

Refernces

• 1、 -. "PROCESS FOR THE STEPWISE SYNTHESIS OF SILAHYDROCARBONS". Page/Page column 54; 57. . Retrieved 2021/12/08.
• 2、 Chen, Yi,Li, Yongming,Xu, Caihong. "Facile preparation of hydrochlorosilane by alkali metal halide catalyzed Si-H/Si-Cl redistribution reaction". supporting information. . Retrieved 2020/09/21.