Ammonium dibenzyl phosphate

Base Information

• Chemical Name: Ammonium dibenzyl phosphate
• CAS No.: 1277151-44-6
• Molecular Formula: C₁₄H₁₅O₄P*H₃N
• Molecular Weight: 295.275
• UNII: P9AWN55JN7
• Wikidata: Q27286409
• Mol file: 1277151-44-6.mol

Synonyms:Ammonium dibenzyl phosphate;1277151-44-6;azanium;dibenzyl phosphate;Phosphoric acid, bis(phenylmethyl) ester, ammonium salt (1:1);P9AWN55JN7;UNII-P9AWN55JN7;Ammoniumdibenzylphosphate;C14H18NO4P;SCHEMBL7268743;CBC15144;AKOS022189385;DB-141276;C72143;A889159;Q27286409

Chemical Property of Ammonium dibenzyl phosphate

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 295.09734505
• Heavy Atom Count: 20
• Complexity: 262

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)COP(=O)([O-])OCC2=CC=CC=C2.[NH4+]

Technology Process of Ammonium dibenzyl phosphate

There total 2 articles about Ammonium dibenzyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

dibenzyl 2-bromo-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl phosphate (1277151-43-5) → 1H,1H,2H-perfluorodecene (21652-58-4) + ammonium dibenzyl phosphate (1277151-44-6)

Guidance literature:

With ammonium formate; zinc; In tetrahydrofuran; acetonitrile; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol2003435

Reference yield:

Dibenzyl N,N-diisopropylphosphoramidite (108549-23-1) → ammonium dibenzyl phosphate (1277151-44-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 1H-tetrazole / acetonitrile / 0 - 20 °C / Inert atmosphere

2: 3-chloro-benzenecarboperoxoic acid / dichloromethane; acetonitrile / -40 - 20 °C / Inert atmosphere

3: ammonium formate; zinc / tetrahydrofuran; acetonitrile / 2 h / 20 °C / Inert atmosphere

With 1H-tetrazole; ammonium formate; 3-chloro-benzenecarboperoxoic acid; zinc; In tetrahydrofuran; dichloromethane; acetonitrile;

DOI:10.1021/ol2003435

upstream raw materials:

dibenzyl 2-bromo-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl phosphate

Dibenzyl N,N-diisopropylphosphoramidite

Refernces