13-Ketobehenic acid methyl ester

Base Information

• Chemical Name: 13-Ketobehenic acid methyl ester
• CAS No.: 2388-99-0
• Molecular Formula: C₂₃H₄₄O₃
• Molecular Weight: 368.601
• Mol file: 2388-99-0.mol

Synonyms:13-Ketobehenic acid methyl ester;13-Oxodocosanoic acid methyl ester

Chemical Property of 13-Ketobehenic acid methyl ester

Chemical Property:

• PSA: 43.37000
• LogP: 7.16030

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 13-Ketobehenic acid methyl ester

There total 5 articles about 13-Ketobehenic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

methyl 12-(3-octyloxiran-2-yl)dodecanoate (87575-32-4) → methyl 13-oxodocosanoate (2388-99-0)

Guidance literature:

With lithium perchlorate; tetraethylammonium perchlorate; In 1,2-dichloro-ethane; at 65 ℃; electrolysis, platinum electrodes, 0.23 F/mol;

DOI:10.1016/S0040-4039(00)88043-0

Reference yield:

methyl cis-13-docosenoate (1120-34-9) → methyl 13-oxodocosanoate (2388-99-0) + methyl 14-oxodocosanoate (54527-15-0)

Guidance literature:

With oxygen; palladium dichloride; In N,N-dimethyl acetamide; water; at 70 ℃; for 48h; under 7500.75 Torr; High pressure; Green chemistry;

DOI:10.1039/c3gc41921e

Reference yield:

cis-methyl 12-(3-octyloxiran-2-yl)dodecanoate (6084-74-8,6084-75-9,87575-32-4) → methyl 13-oxodocosanoate (2388-99-0) + methyl 14-oxodocosanoate (54527-15-0)

Guidance literature:

With Nafion, SAC-13 (Nafion-silica composite); for 2h; Inert atmosphere; Reflux;

DOI:10.1039/c9cy01899a

upstream raw materials:

caprinaldehyde

methyl 11-dodecenoate

methyl 12-(3-octyloxiran-2-yl)dodecanoate

methyl cis-13-docosenoate

Downstream raw materials:

13-hydroxy-docosanoic acid

Refernces

• 1、 Winkler, Matthias,Meier, Michael A. R.. "Highly efficient oxyfunctionalization of unsaturated fatty acid esters: An attractive route for the synthesis of polyamides from renewable resources". supporting information. p. 1784 - 1788. Retrieved 2014/04/17.