Disodium tris(1 2-benzenediolato-O O/')-

Base Information

• Chemical Name: Disodium tris(1 2-benzenediolato-O O/')-
• CAS No.: 101519-12-4
• Molecular Formula: Na2Si(O2C6H4)3
• Molecular Weight: 398.355
• European Community (EC) Number: 631-297-0
• DSSTox Substance ID: DTXSID20451090
• Mol file: 101519-12-4.mol

Synonyms:101519-12-4;DISODIUM TRIS(1 2-BENZENEDIOLATO-O O/')-;AGN-PC-0NE395;DTXSID20451090;TUOBPRJVJQCTTK-UHFFFAOYSA-N

Chemical Property of Disodium tris(1 2-benzenediolato-O O/')-

Chemical Property:

• Melting Point: >400 °C(lit.)
• PSA: 55.38000
• LogP: 3.73760
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 398.01985320
• Heavy Atom Count: 27
• Complexity: 453

Purity/Quality:

97% ^*data from raw suppliers

DISODIUM TRIS(1,2-BENZENEDIOLATO-O,O')SILICATE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)O[Si-2]34(O2)(OC5=CC=CC=C5O3)OC6=CC=CC=C6O4.[Na+].[Na+]

Technology Process of Disodium tris(1 2-benzenediolato-O O/')-

There total 1 articles about Disodium tris(1 2-benzenediolato-O O/')- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9) → sodiumtris(benzene-1,2 diolato)silicate (101519-12-4)

Guidance literature:

With sodium methylate; silica gel; In methanol; for 18h; Heating;

Reference yield: 100.0%

sodiumtris(benzene-1,2 diolato)silicate (101519-12-4) → monosilane (7440-21-3)

Guidance literature:

With lithium aluminium tetrahydride; In further solvent(s); Si-complex in n-Bu2O is treated with a soln. of LiAlH4 in n-Bu2O.; A gas evolved and is collected in a measuring glass tube filled with inert oil.;

DOI:10.1021/om00095a023

Reference yield: 83.0%

C15H33NO6*2C4H9BrMg + sodiumtris(benzene-1,2 diolato)silicate (101519-12-4) → tri-nBu-(2-hydroxyphenoxy)silane (101541-83-7)

Guidance literature:

In diethyl ether; at 20 ℃; for 5h; further carbonyl compounds, further Grignard/TDA-1 complexes, further solvents;

DOI:10.1016/0040-4020(89)80044-4

upstream raw materials:

benzene-1,2-diol

Downstream raw materials:

1,1,1-triethyl-2,2,2-triphenyl-disilane

triethylsilane

triethylsilyl chloride

1-triethylsilyloxy-2-hydroxybenzene

Refernces

• 1、 Boudin, Alain,Cerveau, Genevieve,Chuit, Claude,Corriu, Robert J. P.,Reye, Catherine. "Umsetzung von Grignard-Reagentien mit dianionischen, sechsfach koordinierten Si-Komplexen: Organosilicium-Verbindungen aus Kieselgel". . p. 473 - 474. Retrieved 2007/10/02.