S-N-BUTYL THIOACETATE

Base Information

• Chemical Name: S-N-BUTYL THIOACETATE
• CAS No.: 928-47-2
• Molecular Formula: C6H12OS
• Molecular Weight: 132.227
• Hs Code.: 2930909090
• Mol file: 928-47-2.mol

Synonyms:1-Butanethiol,acetate (6CI);Acetic acid, thio-, S-butyl ester (7CI,8CI);NSC 83554;S-Butylthioacetate;

Chemical Property of S-N-BUTYL THIOACETATE

Chemical Property:

• Vapor Pressure: 2.67mmHg at 25°C
• Refractive Index: 1.4589
• Boiling Point: 164.9 °C at 760 mmHg
• Flash Point: 48.8 °C
• PSA: 42.37000
• Density: 0.953 g/cm³
• LogP: 2.06620

Purity/Quality:

99% ^*data from raw suppliers

S-butylethanethioate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R10:Flammable.
• Hazard Codes: R10:Flammable.
• Statements: R10:Flammable.
• Safety Statements: S23:Do not inhale gas/fumes/vapour/spray.; S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-N-BUTYL THIOACETATE

There total 7 articles about S-N-BUTYL THIOACETATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

1-butyl-3-methylimidazolium Tetrafluoroborate (174501-65-6) + potassium thioacetate (10387-40-3) → S-methyl thiolacetate (1534-08-3) + S-butyl ethanethioate (928-47-2) + 1-butyl-3-methyl-1H-imidazole-2(3H)-thione (119393-94-1)

Guidance literature:

for 0.166667h; microwave irradiation;

DOI:10.1080/00397910601038947

Reference yield: 27.0%

Acetyl bromide (506-96-7) + n-butane (106-97-8,9003-29-6,9021-92-5) → S-propyl thiol-acetate (2307-10-0) + S-butyl ethanethioate (928-47-2) + pentyl thioacetate (2432-32-8)

Guidance literature:

With aluminum tri-bromide; In various solvent(s); at 20 ℃; for 2h; Yield given;

DOI:10.1007/BF00959637

Reference yield: 8.0%

vinyl acetate (108-05-4,9003-20-7) + n-butanethiol (109-79-5) → 1,1-bis(butylthio)ethane (1663-62-3) + S-butyl ethanethioate (928-47-2) + 2-Butylthioethyl acetate (52221-38-2) + acetaldehyde (75-07-0,9002-91-9)

Guidance literature:

With dimanganese decacarbonyl; at 140 ℃; for 5h; Product distribution; other initiator, other alkenyl acetate;

DOI:10.1007/BF00957180

upstream raw materials:

2-methyl-1,3-oxathiolane

ethene

vinyl acetate

n-butanethiol

Downstream raw materials:

n-Butylthiostearat

(3-butylthiophenyl)-acetonitrile

perfluoro-1-butanesulfonyl fluoride

n-butanethiol

Refernces

• 1、 Orlinkov, A. V.,Akhrem, I. S.,Afanas'eva, L. V.,Vitt, S. V.,Vol'pin, M. E.. "FUNCTIONALIZATION OF SATURATED HYDROCARBONS IN THE PRESENCE OF APROTIC ORGANIC SUPERACIDS. 2. SINGLE-STAGE SYNTHESIS OF THIOESTERS R1CO-SR FROM n-ALKANES OR CYCLOALKANES (RH), ELEMENTAL SULFUR, AND COMPLEXES R1COBr*2AlBr3". . p. 90 - 92. Retrieved 2007/10/02.
• 2、 Germash, A. V.,Dostovalova, V. I.,Zorin, V. V.,Terent'ev, A. B.. "INVESTIGATION OF THE STRUCTURE OF THE PRODUCTS FROM TELOMERIZATION OF ETHYLENE WITH 1,3-DIHETEROCYCLOPENTANES BY THE 13C NMR METHOD". . p. 149 - 153. Retrieved 2007/10/02.