1-Ethyl-3-methylimidazolium bicarbonate

Base Information

• Chemical Name: 1-Ethyl-3-methylimidazolium bicarbonate
• CAS No.: 947601-94-7
• Molecular Formula: C7H12N2O3
• Molecular Weight: 172.184
• Hs Code.: 2933290090
• Mol file: 947601-94-7.mol

Synonyms:1-Ethyl-3-methylimidazolium bicarbonate;1-Ethyl-3-methylimidazolium hydrogen carbonate;1-Ethyl-3-methylimidazolium hydrogencarbonate solution

Chemical Property of 1-Ethyl-3-methylimidazolium bicarbonate

Chemical Property:

• Flash Point: 57 °C
• PSA: 69.17000
• LogP: -0.77980

Purity/Quality:

98%Min ^*data from raw suppliers

1-ETHYL-3-METHYLIMIDAZOLIUM BICARBONATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn,T,Xi
• Statements: 20/21/22-36/37/38-68/20/21/22-39/23/24/25
• Safety Statements: 26-36/37

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Ethyl-3-methylimidazolium bicarbonate

There total 5 articles about 1-Ethyl-3-methylimidazolium bicarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

potassium hydrogencarbonate (298-14-6) + 3-ethyl-1-methyl-1H-imidazol-3-ium bromide (65039-08-9) → 1-ethyl-3-methyl-1H-imidazol-3-ium hydrogencarbonate (947601-94-7)

Guidance literature:

Ionic liquid; Green chemistry;

DOI:10.1055/s-0033-1338975

Reference yield: 84.0%

potassium carbonate (584-08-7) + 1-ethyl-3-methyl-1H-imidazol-3-ium chloride (65039-09-0) → 1-ethyl-3-methyl-1H-imidazol-3-ium hydrogencarbonate (947601-94-7)

Guidance literature:

In methanol; at 20 ℃; for 6h;

DOI:10.1016/j.apcata.2011.07.016

Reference yield: 60.0%

potassium hydrogencarbonate (298-14-6) + 1-ethyl-3-methyl-1H-imidazol-3-ium chloride (65039-09-0) → 1-ethyl-3-methyl-1H-imidazol-3-ium hydrogencarbonate (947601-94-7)

Guidance literature:

In methanol; for 48h; Inert atmosphere; Schlenk technique;

DOI:10.1021/jo301597h

upstream raw materials:

1-ethyl-3-methylimidazolium-2-carboxylate

[C₂mim][H(OAc)2][C₂mim(+)-COO(-)]

potassium carbonate

1-ethyl-3-methyl-1H-imidazol-3-ium chloride

Refernces

• 1、 Liu, Jia,Yang, Guoqiang,Liu, Ying,Wu, Dongsheng,Hu, Xingbang,Zhang, Zhibing. "Metal-free imidazolium hydrogen carbonate ionic liquids as bifunctional catalysts for the one-pot synthesis of cyclic carbonates from olefins and CO2". supporting information. p. 3834 - 3838. Retrieved 2019/07/31.
• 2、 Fevre, Mareva,Coupillaud, Paul,Miqueu, Karinne,Sotiropoulos, Jean-Marc,Vignolle, Joan,Taton, Daniel. "Imidazolium hydrogen carbonates versus imidazolium carboxylates as organic precatalysts for N-heterocyclic carbene catalyzed reactions". . p. 10135 - 10144. Retrieved 2013/01/15.