[p-(dimethylamino)phenyl]lithium

Base Information

• Chemical Name: [p-(dimethylamino)phenyl]lithium
• CAS No.: 13190-50-6
• Molecular Formula: C8H10 Li N
• Molecular Weight: 127.115
• Mol file: 13190-50-6.mol

Synonyms:Aniline,N,N-dimethyl-, p-Li deriv. (7CI); Lithium, [p-(dimethylamino)phenyl]-(6CI,8CI); Benzenamine, N,N-dimethyl-, lithium complex;4-Dimethylaminophenyllithium; N,N-Dimethyl-p-lithioaniline;[p-(Dimethylamino)phenyl]lithium; p-N,N-Dimethylaminophenyllithium

Chemical Property of [p-(dimethylamino)phenyl]lithium

Chemical Property:

• PSA: 3.24000
• LogP: 1.47360

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [p-(dimethylamino)phenyl]lithium

There total 3 articles about [p-(dimethylamino)phenyl]lithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromo-N,N-dimethylaniline (586-77-6) → 4-dimethylaminophenyllithium (13190-50-6)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane;

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + N,N-dimethyl-aniline (121-69-7,77733-26-7) → 4-dimethylaminophenyllithium (13190-50-6)

Guidance literature:

Reference yield:

→ 4-dimethylaminophenyllithium (13190-50-6)

Guidance literature:

DOI:10.1021/jo01274a062

upstream raw materials:

n-butyllithium

N,N-dimethyl-aniline

4-bromo-N,N-dimethylaniline

Downstream raw materials:

N,N-dimethyl-4-(pyridin-2-yl)aniline

2-(4-(dimethylamino)phenyl)quinoline

1,3-bis-(4-dimethylamino-phenyl)-propan-2-ol

4-benzo[b]arsindol-5-yl-N,N-dimethyl-aniline

Refernces

• 1、 -. "Chiral phosphines". . . Retrieved 2008/06/13.