Cyclopentyloxybenzene

Base Information

• Chemical Name: Cyclopentyloxybenzene
• CAS No.: 33186-68-4
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Mol file: 33186-68-4.mol

Synonyms:Cyclopentyloxybenzene

Chemical Property of Cyclopentyloxybenzene

Chemical Property:

• Vapor Pressure: 0.0591mmHg at 25°C
• Boiling Point: 240.3°C at 760 mmHg
• Flash Point: 89.6°C
• PSA: 9.23000
• Density: 1.025g/cm³
• LogP: 3.00800

Purity/Quality:

98% ^*data from raw suppliers

(cyclopentyloxy)benzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclopentyloxybenzene

There total 7 articles about Cyclopentyloxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

Cyclopentanol (96-41-3) + methylphenylsulfonate (3112-85-4) → cyclopentyl phenyl ether (33186-68-4)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; at 80 ℃; for 36h; chemoselective reaction; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.1c01926

Reference yield: 86.0%

Cyclopentanol (96-41-3) + phenol (108-95-2,27073-41-2) → cyclopentyl phenyl ether (33186-68-4)

Guidance literature:

With diazene-1,2-diylbis(morpholinomethanone); tributylphosphine; In tetrahydrofuran; at 20 ℃; for 16h; Inert atmosphere;

DOI:10.1016/j.tetlet.2013.06.049

Reference yield: 66.0%

cyclohexenone (930-68-7) + Cyclopentanol (96-41-3) → cyclopentyl phenyl ether (33186-68-4)

Guidance literature:

With iodine; dimethyl sulfoxide; In nitromethane; at 130 ℃; for 24h; Schlenk technique; Sealed tube;

DOI:10.1002/cjoc.201700743

upstream raw materials:

Cyclopentyl bromide

potassium phenolate

cyclopentene

phenol

Downstream raw materials:

Cyclopentanol

4-cyclopentylphenol

meta-cyclopentylphenol

phenol

Refernces

• 1、 Liang, Yu-Feng,Yuan, Yizhi,Shen, Tao,Song, Song,Jiao, Ning. "Metal-Free I2-Catalyzed Highly Selective Dehydrogenative Coupling of Alcohols and Cyclohexenones". . p. 233 - 240. Retrieved 2018/02/19.
• 2、 Drabkin, A. E.,Fedotov, A. S.,Fedotova, N. F.. "ALKYLATION OF PHENOL WITH CYCLOOLEFINS IN THE PRESENCE OF GLYCERYL SULFATE". . p. 698 - 700. Retrieved 2007/10/02.