2-Ethyl-1,3-dioxolane

Base Information

• Chemical Name: 2-Ethyl-1,3-dioxolane
• CAS No.: 2568-96-9
• Molecular Formula: C5H10 O2
• Molecular Weight: 102.133
• Hs Code.: 2932999099
• European Community (EC) Number: 219-910-6
• DSSTox Substance ID: DTXSID80180374
• Nikkaji Number: J121.080G
• Wikidata: Q83050903
• Mol file: 2568-96-9.mol

Synonyms:2-ETHYL-1,3-DIOXOLANE;2568-96-9;1,3-Dioxolane, 2-ethyl-;2-Ethyldioxolane;EINECS 219-910-6;Propanal, cyclic 1,2-ethanediyl acetal;2-ethyl-1,3-dioxolan;SCHEMBL26404;DTXSID80180374;MFCD00792514;AKOS006275602;FS-6482;FT-0691658

Chemical Property of 2-Ethyl-1,3-dioxolane

Chemical Property:

• Vapor Pressure: 26.7mmHg at 25°C
• Boiling Point: 111.5°Cat760mmHg
• Flash Point: 21.5°C
• PSA: 18.46000
• Density: 0.942g/cm³
• LogP: 0.76930
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 102.068079557
• Heavy Atom Count: 7
• Complexity: 48

Purity/Quality:

99% ^*data from raw suppliers

2-Ethyl-1,3-dioxolane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC1OCCO1
• Uses: 2-Ethyldioxolane is a chemical found in volatile oil fruit of Cinnamomun camphora.

Technology Process of 2-Ethyl-1,3-dioxolane

There total 14 articles about 2-Ethyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

ethylene glycol (107-21-1) + propionaldehyde (123-38-6) → 2-ethyl-1,3-dioxolane (2568-96-9)

Guidance literature:

With MNPsSi-PPh₃-SO₃H magnetic nano-solid acid catalyst; In cyclohexane; at 80.84 ℃; for 2h;

DOI:10.1007/s10562-010-0271-x

Reference yield: 40.0%

2-ethoxy-1,3-dioxolane (4544-20-1) + triethylaluminum (97-93-8) → 2-ethyl-1,3-dioxolane (2568-96-9) + 2-(1-Ethoxy-propoxy)-ethanol

Guidance literature:

With diisobutylaluminium hydride; In hexane; at 35 - 40 ℃;

Reference yield:

1,3-DIOXOLANE (646-06-0) + ethene (74-85-1) → 2-ethyl-1,3-dioxolane (2568-96-9) + 2-butyl-1,3-dioxolane (4360-76-3) + 2-hexyl-1,3-dioxolane (1708-34-5) + hexyl formate (629-33-4) + n-butyl formate (592-84-7) + octyl formate (112-32-3)

Guidance literature:

di-tert-butyl peroxide; at 140 - 150 ℃; Product distribution;

DOI:10.1007/BF01167778

upstream raw materials:

ethylene glycol monoallyl ether

(E)-2-(1-propenyloxy)ether

ethylene glycol

propionaldehyde

Downstream raw materials:

ethylene glycol

propionaldehyde

2-propoxyethanol

1,2-di-n-propoxyethane

Refernces

• 1、 Krompiec, Stanislaw,Penkala, Mateusz,Kowalska, Ewelina,Penczek, Robert,Bujak, Piotr,Danikiewicz, Witold,Spolnik, Grzegorz,Kita, Andrzej,Grudzka, Iwona. "Synthesis of unsymmetrical alkyl acetals via addition of primary alcohols to allyl ethers mediated by ruthenium complexes". experimental part. p. 1241 - 1247. Retrieved 2012/06/04.
• 2、 Dai, Yan,Li, Bin Dong,Quan, Heng Dao,Lü, Chun Xu. "[Hmim]3PW12O40: A high-efficient and green catalyst for the acetalization of carbonyl compounds". experimental part. p. 678 - 681. Retrieved 2011/10/31.