1-Phenylcycloocta1,3,5,7-tetrene

Base Information

• Chemical Name: 1-Phenylcycloocta1,3,5,7-tetrene
• CAS No.: 4603-00-3
• Molecular Formula: C14H12
• Molecular Weight: 180.249
• Mol file: 4603-00-3.mol

Synonyms:1-Phenylcycloocta1,3,5,7-tetrene;1-Phenylcyclooctatetraene

Chemical Property of 1-Phenylcycloocta1,3,5,7-tetrene

Chemical Property:

• Boiling Point: 58 - 59 °C (0.005 mmHg)
• PSA: 0.00000
• LogP: 3.75220

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Phenylcycloocta1,3,5,7-tetrene

There total 16 articles about 1-Phenylcycloocta1,3,5,7-tetrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

polyethylene → phenyl-cyclooctatetraene (4603-00-3) + dibenzo[a,h]anthracene (53-70-3) + dimethyl-1,2 naphtalene (573-98-8) + 1-(1-cyclopenten-1-yl)-naphthalene (58195-37-2)

Guidance literature:

With air; at 900 ℃; Further byproducts given; Formation of xenobiotics;

DOI:10.1016/S0045-6535(99)00054-5

Reference yield:

phenylacetylene (536-74-3) → phenyl-cyclooctatetraene (4603-00-3)

Guidance literature:

With nickel cyanide; calcium carbide; acetylene; at 70 - 90 ℃; under 7355.08 - 14710.2 Torr; Reagens 4: THF;

DOI:10.1021/ja01121a046

Reference yield:

cyclooctatetraene (477773-51-6) + phenyllithium (591-51-5) → phenyl-cyclooctatetraene (4603-00-3)

Guidance literature:

With diethyl ether; at 90 ℃;

DOI:10.1021/ja01151a125

upstream raw materials:

cyclooctatetraene

phenyllithium

phenylacetylene

1,3,5,7-cyclooctatetraene

Downstream raw materials:

[Cr(CO)3(C₆H₅C₈H₇)]

Ru(Si(CH₃)3)(CO)2(C₈H₇C₆H₅(Si(CH₃)3))

Refernces

• 1、 Piao, Mingjun,Chu, Shaogang,Zheng, Minghui,Xu, Xiaobai. "Characterization of the combustion products of polyethylene". . p. 1497 - 1512. Retrieved 2007/10/03.
• 2、 Stevenson, Gerald R.,Nebgen, Mark A.. "Heats of Generation of Substituted Annulene Dianions". . p. 5509 - 5513. Retrieved 2007/10/02.