10-bromoanthracene-9-carboxylic Acid

Base Information

• Chemical Name: 10-bromoanthracene-9-carboxylic Acid
• CAS No.: 6929-81-3
• Molecular Formula: C15H9BrO2
• Molecular Weight: 301.139
• Hs Code.: 2916399090
• European Community (EC) Number: 635-316-3
• DSSTox Substance ID: DTXSID80399166
• Nikkaji Number: J1.920.797H
• Wikidata: Q82201557
• Mol file: 6929-81-3.mol

Synonyms:10-bromoanthracene-9-carboxylic Acid;6929-81-3;10-bromo-9-anthracenecarboxylic acid;10-Bromoanthracene-9-carboxylicacid;SCHEMBL125964;DTXSID80399166;10-bromoanthracene-9-carboxylic acid;AKOS016013668;BS-53018;CS-0188408;E76211;A866875

Chemical Property of 10-bromoanthracene-9-carboxylic Acid

Chemical Property:

• Melting Point: 273 °C
• Boiling Point: 513.9±23.0 °C(Predicted)
• PKA: 3.37±0.30(Predicted)
• PSA: 37.30000
• Density: 1.615±0.06 g/cm3(Predicted)
• LogP: 4.45370
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 299.97859
• Heavy Atom Count: 18
• Complexity: 307

Purity/Quality:

HPLC≥98% ^*data from raw suppliers

10-BROMO-9-ANTHRACENECARBOXYLIC ACID Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(=C3C=CC=CC3=C2Br)C(=O)O

Technology Process of 10-bromoanthracene-9-carboxylic Acid

There total 5 articles about 10-bromoanthracene-9-carboxylic Acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

anthracen-9-carboxylic acid (723-62-6) → 10-bromo-9-anthracenecarboxylic acid (6929-81-3)

Guidance literature:

With bromine; acetic acid; at 60 ℃; for 4h;

Reference yield: 84.0%

carbon dioxide (124-38-9,18923-20-1) + 9,10-Dibromoanthracene (523-27-3) → 10-bromo-9-anthracenecarboxylic acid (6929-81-3)

Guidance literature:

9,10-Dibromoanthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

carbon dioxide; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

Reference yield:

anthracen-9-carboxylic acid (723-62-6) + bromine (7726-95-6) → 9,10-Dibromoanthracene (523-27-3) + 10-bromo-9-anthracenecarboxylic acid (6929-81-3)

Guidance literature:

upstream raw materials:

anthracen-9-carboxylic acid

9,10-Dibromoanthracene

bromine

carbon dioxide

Downstream raw materials:

9-tert-butyl anthroate

ethyl 10-bromoanthracene-9-carboxylate

Refernces

• 1、 Rice, Anthony T.,Martin, Maxwell I.,Warndorf, Molly C.,Yap, Glenn P. A.,Rosenthal, Joel. "Synthesis, Spectroscopic, and 1O2Sensitization Characteristics of Extended Pd(II) 10,10-Dimethylbiladiene Complexes Bearing Alkynyl-Aryl Appendages". supporting information. p. 11154 - 11163. Retrieved 2021/08/03.
• 2、 -. "Novel synthesis method for 5-[10-(9-carbosyl anthryl)]-isophthalic acid". Paragraph 0023. . Retrieved 2017/03/08.