1,2,4-Benzenetricarbonyl trichloride

Base Information

• Chemical Name: 1,2,4-Benzenetricarbonyl trichloride
• CAS No.: 3867-55-8
• Molecular Formula: C9H3Cl3O3
• Molecular Weight: 265.48
• Hs Code.: 2917399090
• European Community (EC) Number: 223-386-4
• DSSTox Substance ID: DTXSID7063213
• Nikkaji Number: J60.342B
• Wikidata: Q81990573
• Mol file: 3867-55-8.mol

Synonyms:1,2,4-Benzenetricarbonyl trichloride;3867-55-8;benzene-1,2,4-tricarbonyl chloride;benzene-1,2,4-tricarbonyl trichloride;trimellityl trichloride;trimellitic acid chloride;EINECS 223-386-4;C24H27N5O4;trimellitic chloride;trimellitoyl chloride;trimellitic acid trichloride;SCHEMBL75886;DTXSID7063213;benzene-1,2,4-tricarbonyltrichloride

Chemical Property of 1,2,4-Benzenetricarbonyl trichloride

Chemical Property:

• Vapor Pressure: 7.27E-06mmHg at 25°C
• Refractive Index: 1.59
• Boiling Point: 376.4 °C at 760 mmHg
• Flash Point: 159.1 °C
• PSA: 51.21000
• Density: 1.574 g/cm³
• LogP: 2.82360
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 263.914777
• Heavy Atom Count: 15
• Complexity: 303

Purity/Quality:

99%, ^*data from raw suppliers

1,2,4-BENZENETRICARBONYLTRICHLORIDE 95 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=C(C=C1C(=O)Cl)C(=O)Cl)C(=O)Cl

Technology Process of 1,2,4-Benzenetricarbonyl trichloride

There total 2 articles about 1,2,4-Benzenetricarbonyl trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2,4-benzene tricarboxylic acid (528-44-9) → trimellitic trichloride (3867-55-8)

Guidance literature:

With phosphorus pentachloride; at 150 ℃; for 24h;

DOI:10.1021/jp9093063

Reference yield:

→ trimellitic trichloride (3867-55-8)

Guidance literature:

Phthalsaeureanhydrid-4-carbonsaeure, COCl2 in Bzl., etwas DMF;

DOI:10.1021/jo00954a034

Reference yield: 88.0%

trimellitic trichloride (3867-55-8) + 4'-(pentyloxy)[1,1'-biphenyl]-4-ol (122163-84-2) → 1,2,4-tris(4'-n-amyloxybiphenyl-4-yloxycarbonyl)benzene

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 5h;

DOI:10.1080/15421400902841247

upstream raw materials:

1,2,4-benzene tricarboxylic acid

Downstream raw materials:

Trimellithsaeure-tris-ethoxyethylester

Benzene-1,2,4-tricarboxylic acid tris-(4-heptyloxy-phenyl) ester

Benzene-1,2,4-tricarboxylic acid tris-(4-octyloxy-phenyl) ester

Benzene-1,2,4-tricarboxylic acid tris-(4-decyloxy-phenyl) ester

Refernces