S-Phenyl-S-vinyl-N-(p-toluenesulfonyl)sulfilimine

Base Information

• Chemical Name: S-Phenyl-S-vinyl-N-(p-toluenesulfonyl)sulfilimine
• CAS No.: 56692-06-9
• Molecular Formula: C15H15NO2S2
• Molecular Weight: 305.422
• Mol file: 56692-06-9.mol

Synonyms:S-Phenyl-S-vinyl-N-(p-toluenesulfonyl)sulfilimine

Chemical Property of S-Phenyl-S-vinyl-N-(p-toluenesulfonyl)sulfilimine

Chemical Property:

• Melting Point: 111-113 °C (decomp)
• Boiling Point: 481.1±38.0 °C(Predicted)
• PSA: 74.09000
• Density: 1.21±0.1 g/cm3(Predicted)
• LogP: 5.41960

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of S-Phenyl-S-vinyl-N-(p-toluenesulfonyl)sulfilimine

There total 11 articles about S-Phenyl-S-vinyl-N-(p-toluenesulfonyl)sulfilimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloroamine-T (127-65-1) → S-ethenyl-S-phenyl-N-(toluene-4-sulfonyl)sulfilimine (56692-06-9)

Guidance literature:

Multi-step reaction with 2 steps

2: Et₃N

With triethylamine;

DOI:10.1246/cl.1975.581

Reference yield:

2-(phenylthio)ethanol (699-12-7) → S-ethenyl-S-phenyl-N-(toluene-4-sulfonyl)sulfilimine (56692-06-9)

Guidance literature:

Multi-step reaction with 3 steps

3: NaH / tetrahydrofuran

With sodium hydride; In tetrahydrofuran;

DOI:10.1246/bcsj.52.841

Reference yield:

sodium thiophenolate (930-69-8) → S-ethenyl-S-phenyl-N-(toluene-4-sulfonyl)sulfilimine (56692-06-9)

Guidance literature:

Multi-step reaction with 4 steps

4: NaH / tetrahydrofuran

With sodium hydride; In tetrahydrofuran;

DOI:10.1246/bcsj.52.841

upstream raw materials:

C₁₇H₁₉NO₄S₂

chloroamine-T

phenylthioethylene

S-(2-Bromethyl)-S-p-tolyl-N-tosylsulfilimin

Downstream raw materials:

S-(2-phenothiazin-10-yl-ethyl)-S-phenyl-N-(toluene-4-sulfonyl)-sulfimide

S-<2-(Phenylthio)aethyl>-S-phenyl-N-p-tosylsulfilimin

C₂₀H₂₆N₂O₂S₄

ethyl 1-acetylcyclopropanecarboxylate

Refernces

• 1、 Huang, Zhongxing,Dong, Guangbin. "Palladium-catalyzed redox cascade for direct β-arylation of ketones". . p. 3253 - 3265. Retrieved 2018/05/04.