7-iodohept-1-ene

Base Information

• Chemical Name: 7-iodohept-1-ene
• CAS No.: 107175-49-5
• Molecular Formula: C₇H₁₃I
• Molecular Weight: 224.085
• Mol file: 107175-49-5.mol

Synonyms:7-iodohept-1-ene

Chemical Property of 7-iodohept-1-ene

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 7-iodohept-1-ene

There total 1 articles about 7-iodohept-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

7-bromo-hept-1-ene (4117-09-3) → 6-hepten-1-yl iodide (107175-49-5)

Guidance literature:

With sodium iodide; In acetone; for 2.5h; Heating;

DOI:10.1021/ja00242a032

Reference yield: 83.0%

Trifluoro-methanesulfonate4-methoxy-1-{[(E)-(S)-1-methoxymethyl-2-methyl-propylimino]-phenyl-methyl}-pyridinium; + 6-hepten-1-yl iodide (107175-49-5) → 2-hept-6-enyl-1-((E)-{((1S)-1-(methoxymethyl)-2-methylpropyl)imino}(phenyl)methyl)-2,3-dihydropyridin-4(1H)-one

Guidance literature:

6-hepten-1-yl iodide; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 1h;

With magnesium bromide; In diethyl ether; pentane; at 20 ℃; for 1h;

Trifluoro-methanesulfonate4-methoxy-1-{[(E)-(S)-1-methoxymethyl-2-methyl-propylimino]-phenyl-methyl}-pyridinium;; In diethyl ether; dichloromethane; pentane; at -20 ℃;

DOI:10.1021/ol0609006

Reference yield: 66.0%

4-vinylbenzyl chloride (1073-67-2,24991-47-7) + 6-hepten-1-yl iodide (107175-49-5) + phenylzinc iodide (23665-09-0) → 1-chloro-4-(1-phenylnon-8-en-1-yl)benzene

Guidance literature:

With nickel dibromide; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 6h; regioselective reaction; Glovebox; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.8b05374

upstream raw materials:

7-bromo-hept-1-ene

Downstream raw materials:

1-Heptene

methyl cyclohexane

non-1-en-8-yne

bilobol

Refernces

• 1、 Schoening, A.,Friedrichsen, W.. "INTRAMOLEKULARE CYCLOADDITIONEN MIT ISOBENZOFURANEN - III. EIN HYDRIERTES NAPHTHOTHIOPHEN AUS EINEM 1-ALKENYLTHIENOFURAN". . p. 1137 - 1138. Retrieved 2007/10/02.