Triethylsilanol

Base Information

• Chemical Name: Triethylsilanol
• CAS No.: 597-52-4
• Molecular Formula: C6H16OSi
• Molecular Weight: 132.278
• Hs Code.: 29319090
• European Community (EC) Number: 209-903-6
• UNII: E4HY4NF4Z6
• DSSTox Substance ID: DTXSID4060498
• Nikkaji Number: J98.168K
• Wikidata: Q28473937
• Mol file: 597-52-4.mol

Synonyms:triethylsilane;Triethylsilanol

Chemical Property of Triethylsilanol

Chemical Property:

• Appearance/Colour: Clear colorless to slightly yellow liquid
• Vapor Pressure: 1.2mmHg at 25°C
• Refractive Index: n20/D 1.433(lit.)
• Boiling Point: 154 °C at 760 mmHg
• PKA: 15.18±0.53(Predicted)
• Flash Point: 57.222 °C
• PSA: 20.23000
• Density: 0.822 g/cm³
• LogP: 1.98390
• Storage Temp.: 2-8°C
• Water Solubility.: Practically insoluble in water
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 132.097041664
• Heavy Atom Count: 8
• Complexity: 51.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triethylsilanol ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 23-24/25-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[Si](CC)(CC)O

Technology Process of Triethylsilanol

There total 70 articles about Triethylsilanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

triethylsilane (617-86-7) → Triethylsilanol (597-52-4)

Guidance literature:

With 5%-palladium/activated carbon; water; In ethyl acetate;

DOI:10.1055/s-0035-1561633

Reference yield: 99.0%

triethylsilane (617-86-7) → Triethylsilanol (597-52-4) + hydrogen (1333-74-0)

Guidance literature:

With [Ir(H)(cis-cyclooctene)(CF₃SO₃)(bis(pyridine-2-yloxy)methylsilyl)]; water; In dichloromethane-d2; at 20 ℃; for 0.3h; Solvent; Catalytic behavior;

DOI:10.1002/cctc.201301107

Reference yield: 95.0%

triethylsilyl chloride (994-30-9) → Triethylsilanol (597-52-4)

Guidance literature:

With acetate buffer; for 0.5h; pH=5;

DOI:10.1021/ja7100888

upstream raw materials:

triethylsilane

tetrachloromethane

diethyl ether

triethylsilyl chloride

Downstream raw materials:

pentaethyldisiloxane

triethyl-(1-tert-butoxy-ethoxy)-silane

Decaaethyl-tetrasiloxan

triethyl-(1-phenoxy-ethoxy)-silane

Refernces

• 1、 Spialter,Austin. "". . p. 1975,1976. Retrieved 1966.
• 2、 Arzumanyan, Ashot V.,Goncharova, Irina K.,Novikov, Roman A.,Milenin, Sergey A.,Muzafarov, Aziz M.. "Copper-Catalyzed Oxidation of Hydrosilanes: A New Method for the Synthesis of Alkyl- and Siloxysilanols". . p. 489 - 492. Retrieved 2018.
• 3、 Yang, Fan,Liu, Zhihui,Liu, Xiaodong,Feng, Andong,Zhang, Bing,Yang, Wang,Li, Yongfeng. "Cobalt single atoms anchored on nitrogen-doped porous carbon as an efficient catalyst for oxidation of silanes". . p. 1026 - 1035. Retrieved 2021/02/09.
• 4、 Li, Luyan,Li, Zhixin,Yang, Weijie,Huang, Yamin,Huang, Gang,Guan, Qiaoqiao,Dong, Yemin,Lu, Junling,Yu, Shu-Hong,Jiang, Hai-Long. "Integration of Pd nanoparticles with engineered pore walls in MOFs for enhanced catalysis". . p. 686 - 698. Retrieved 2021/02/27.