4-Bromo-4'-propoxy-1,1'-biphenyl

Base Information

• Chemical Name: 4-Bromo-4'-propoxy-1,1'-biphenyl
• CAS No.: 154020-02-7
• Molecular Formula: C15H15BrO
• Molecular Weight: 291.187
• DSSTox Substance ID: DTXSID20451878
• Wikidata: Q82272160
• Mol file: 154020-02-7.mol

Synonyms:154020-02-7;4-Bromo-4'-propoxy-1,1'-biphenyl;1-(4-Bromophenyl)-4-propoxybenzene;4-Bromo-4'-N-propyloxybiphenyl;1-bromo-4-(4-propoxyphenyl)benzene;SCHEMBL9155411;DTXSID20451878;MFCD19105397;AKOS016008617;4-Bromo-4/'-propoxy-1,1/'-biphenyl;BS-27391;CS-0195134;E91817;A883765

Chemical Property of 4-Bromo-4'-propoxy-1,1'-biphenyl

Chemical Property:

• Boiling Point: 374.7±25.0 °C(Predicted)
• Density: 1.277±0.06 g/cm3(Predicted)
• XLogP3: 5.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 290.03063
• Heavy Atom Count: 17
• Complexity: 203

Purity/Quality:

98.5% ^*data from raw suppliers

1-(4-Bromophenyl)-4-propoxybenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCOC1=CC=C(C=C1)C2=CC=C(C=C2)Br

Technology Process of 4-Bromo-4'-propoxy-1,1'-biphenyl

There total 1 articles about 4-Bromo-4'-propoxy-1,1'-biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.8%

4-bromo-4'-hydroxybiphenyl (29558-77-8) + propyl bromide (106-94-5) → 4-bromo-4'-n-propoxybiphenyl (154020-02-7)

Guidance literature:

With potassium carbonate; In butanone; for 8h; Reflux;

DOI:10.1016/j.ejmech.2012.01.054

Reference yield: 85.0%

4-bromo-4'-n-propoxybiphenyl (154020-02-7) → 4-cyano-4'-propyloxybiphenyl (52709-86-1)

Guidance literature:

With iodophenylbis(triphenylphosphine)palladium; In N,N-dimethyl-formamide; for 2h; Heating;

Reference yield:

bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + 4-bromo-4'-n-propoxybiphenyl (154020-02-7) → 4-biphenylpropoxynorbornene

Guidance literature:

With (bis(tricyclohexyl)phosphine)palladium(II) dichloride; sodium formate; In N,N-dimethyl-formamide; at 120 ℃; Inert atmosphere;

upstream raw materials:

4-bromo-4'-hydroxybiphenyl

propyl bromide

Downstream raw materials:

4-cyano-4'-propyloxybiphenyl

C₄₂H₅₄N₄O₉

C₃₇H₄₆N₄O₇

C₄₃H₅₆N₄O₈

Refernces

• 1、 Kouwer, Paul H. J.,Swager, Timothy M.. "Synthesis and mesomorphic properties of rigid-core ionic liquid crystals". . p. 14042 - 14052. Retrieved 2008/09/17.