TRIPHENYL-D15-PHOSPHINE OXIDE

Base Information

• Chemical Name: TRIPHENYL-D15-PHOSPHINE OXIDE
• CAS No.: 54964-93-1
• Molecular Formula: C18D15OP
• Molecular Weight: 293.171
• Mol file: 54964-93-1.mol

Synonyms:TRIPHENYL-D15-PHOSPHINE OXIDE

Chemical Property of TRIPHENYL-D15-PHOSPHINE OXIDE

Chemical Property:

• Melting Point: 150-157 °C
• Flash Point: 180 °C
• PSA: 26.88000
• LogP: 3.32600

Purity/Quality:

TriphenylphosphineOxide-d15 ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Triphenylphosphine Oxide-d15, is the labeled analogue of Triphenylphosphine Oxide (T808980), (Orlistat USP Related Compound C) and a catalyst in the conversion of aldehydes into 1,1-dichlorides. Triphenylphosphine Oxide is used as a catalyst for the synthesis of hightly functionalized α-CF3 γ-keto esters.

Technology Process of TRIPHENYL-D15-PHOSPHINE OXIDE

There total 2 articles about TRIPHENYL-D15-PHOSPHINE OXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

Triphenylphosphine oxide (791-28-6) → triphenylphosphane oxide-d15 (54964-93-1)

Guidance literature:

platinum(IV) oxide; In water-d2; at 250 ℃; for 12h; under 30002.4 Torr;

DOI:10.3987/COM-05-S(T)36

Reference yield:

triphenylphosphine-d15 (24762-44-5) → triphenylphosphane oxide-d15 (54964-93-1)

Guidance literature:

With dihydrogen peroxide; In methanol;

Reference yield:

4-toluenesulfonyl azide (941-55-9) + triphenylphosphane oxide-d15 (54964-93-1) → C25H7(2)H15NO3PS

Guidance literature:

With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; trimethylpyruvic acid; silver(I) triflimide; at 60 ℃; for 0.5h;

DOI:10.1016/j.tet.2015.02.065

upstream raw materials:

triphenylphosphine-d15

Triphenylphosphine oxide

Refernces

• 1、 Kaim, Wolfgang,Haenel, Peter,Bock, Hans. "The Reduction of Triphenylphosphane Derivatives to their Radical Anions and to the Radical Dianion of Dibenzophosphole". . p. 1382 - 1387. Retrieved 2007/10/02.