Tetrakis(acetonitrile)copper(I) Perchlorate

Base Information

• Chemical Name: Tetrakis(acetonitrile)copper(I) Perchlorate
• CAS No.: 14057-91-1
• Molecular Formula: C8H16ClCuN4O4
• Molecular Weight: 327.207
• Mol file: 14057-91-1.mol

Synonyms:Tetrakis(acetonitrile)copper(I) Perchlorate

Chemical Property of Tetrakis(acetonitrile)copper(I) Perchlorate

Chemical Property:

• PSA: 122.39000
• LogP: 3.18812

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tetrakis(acetonitrile)copper(I) Perchlorate

There total 6 articles about Tetrakis(acetonitrile)copper(I) Perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2,4-ditert-butyl-6-{4-[2-(6,8-ditert-butyl-4H-benzo[e][1,3]oxazin-3-yl)-ethyl]piperazin-1-ylmethyl}phenol (1428241-63-7) + CuH12O6(2+)*2ClO4(1-) + acetonitrile (75-05-8,26809-02-9) → tetrakis(acetonitrile)copper(I) perchlorate (14057-91-1) + 3,5-di-tert-butyl-2-hydroxybenzaldehyde (37942-07-7) + 6,8-di-tert-butyl-3,4-dihydro-3-(2-(piperazin-1-yl)ethyl)-2H-benzo[e][1,3]oxazine (1428241-64-8)

Guidance literature:

for 1h;

DOI:10.1016/j.poly.2012.12.036

Reference yield: 60.0%

[Cu(tris(2-aminoethyl)amine)(acetonitrile)](ClO4)2 → aminoethylpiperazine (140-31-8) + tetrakis(acetonitrile)copper(I) perchlorate (14057-91-1) + tris(2-aminoethyl)ammonium perchlorate

Guidance literature:

With NO; In acetonitrile; NO purged into soln. of Cu complex in degassed CH3CN (O2-free conditions); stirred (10 min, room temp.); NO removed; layered with benzene; cooled;

DOI:10.1016/j.ica.2009.09.048

Reference yield: 30.0%

C17H39CuN5(2+)*2ClO4(1-) → tetrakis(acetonitrile)copper(I) perchlorate (14057-91-1) + C15H33N7O3*ClHO4 (1229530-48-6) + tris[2-(diisopropylamino)ethyl]amine (157794-54-2)

Guidance literature:

With nitrogen(II) oxide; In acetonitrile; at 20 ℃;

DOI:10.1021/ja102279c

upstream raw materials:

2,4-ditert-butyl-6-{4-[2-(6,8-ditert-butyl-4H-benzo[e][1,3]oxazin-3-yl)-ethyl]piperazin-1-ylmethyl}phenol

acetonitrile

Downstream raw materials:

{Cu(2,9-dimethyl-1,10-phenanthroline)(P(C₆H₄OMe-p)3)2}ClO₄

Cu((C₆H₅)C₅H₃NS(CHNC₆H₄(CH₃)))2⁽¹⁺⁾*ClO₄^(1-) = {Cu(C₁₉H₁₆N₂S)2}ClO₄

(4,4'-diphenyl-2,2'-bipyridine)(ethylene) copper perchlorate

[Cu(N-cyclohexyl-N-[(diphenylphosphino)methyl]-2-pyridinamine)2](ClO₄)

Refernces

• 1、 Boiocchi, Massimo,Brega, Valentina,Ciarrocchi, Carlo,Fabbrizzi, Luigi,Pallavicini, Piersandro. "Dicopper double-strand helicates held together by additional π-π Interactions". . p. 10643 - 10652. Retrieved 2013.
• 2、 Sarma, Moushumi,Kalita, Apurba,Kumar, Pankaj,Singh, Amardeep,Mondal, Biplab. "Reduction of copper(II) complexes of tripodal ligands by nitric oxide and trinitrosation of the ligands". supporting information; experimental part. p. 7846 - 7847. Retrieved 2010/08/05.