Lithium aluminum-tri-tert-butoxyhydride

Base Information

• Chemical Name: Lithium aluminum-tri-tert-butoxyhydride
• CAS No.: 17476-04-9
• Molecular Formula: C12H28AlLiO3
• Molecular Weight: 254.27
• Hs Code.: 29055900
• Mol file: 17476-04-9.mol

Synonyms:MFCD00011532;Aluminate(1-), hydrotris(2-methyl-2-propanolato)-, lithium (1:1), (T-4)-;Lithium aluminum-tri-tert-butoxyhydride;SCHEMBL2158;FMSXILLOKUGXFX-UHFFFAOYSA-N;AKOS030228776;Lithium hydridotris(tert-butoxy)aluminate;L0159;Lithium tri-t-butoxyaluminohydride, 1.0M in THF;Lithium hydridotris(tert-butoxy)aluminate, nominally 1M in THF, packaged under Argon in resealable ChemSeal bottles

Chemical Property of Lithium aluminum-tri-tert-butoxyhydride

Chemical Property:

• Appearance/Colour: white powder
• Vapor Pressure: 46mmHg at 25°C
• Melting Point: 300-319 °C (dec.)(lit.)
• Boiling Point: 84.6ºC at 760 mmHg
• Flash Point: 95°F
• PSA: 27.69000
• Density: 0.942 g/mL at 25 °C
• LogP: 3.90990
• Storage Temp.: 2-8°C
• Sensitive.: Air & Moisture Sensitive
• Solubility.: It is soluble in organic solvents at low temperatures.
• Water Solubility.: Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 253.1935616
• Heavy Atom Count: 17
• Complexity: 170

Purity/Quality:

98% ^*data from raw suppliers

Lithium tri-tert-butoxyaluminum hydride solution ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, C
• Hazard Codes: F,C,T
• Statements: 60-61-10-14/15-19-34-14-11-15-35-40-37
• Safety Statements: 53-26-36/37/39-43-45-16-43B-6A

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Li+].CC(C)(C)O[Al-](OC(C)(C)C)OC(C)(C)C
• Uses: antimicrobial, cholesterol lowering agent, for ion-permeable synthetic membranes Lithium tri-tert-butoxyaluminum hydride is less reactive than lithium aluminum hydride (LAH) and is very useful in selective reductions of acyl halides, aldehydes, ketones, and esters. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff. LAH, is a reducing agent commonly employed in modern organic synthesis.