Tetrabutylazanium;trichlorogallane;chloride

Base Information

• Chemical Name: Tetrabutylazanium;trichlorogallane;chloride
• CAS No.: 38555-81-6
• Molecular Formula: C₁₆H₃₆N*Cl₄Ga
• Molecular Weight: 454.004
• Hs Code.: 2923900090
• European Community (EC) Number: 636-816-4
• DSSTox Substance ID: DTXSID30584328
• Mol file: 38555-81-6.mol

Synonyms:38555-81-6;Tetrabutylazanium;trichlorogallane;chloride;DTXSID30584328;Tetrabutylammonium tetrachlorogallate(&;N,N,N-Tributylbutan-1-aminium chloride--trichlorogallane (1/1/1)

Chemical Property of Tetrabutylazanium;trichlorogallane;chloride

Chemical Property:

• Melting Point: 131-134 °C(lit.)
• PSA: 0.00000
• LogP: -7.02370
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 453.08281
• Heavy Atom Count: 22
• Complexity: 124

Purity/Quality:

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[Cl-].Cl[Ga](Cl)Cl

Technology Process of Tetrabutylazanium;trichlorogallane;chloride

There total 3 articles about Tetrabutylazanium;trichlorogallane;chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

gallium (7440-55-3) + tetrabutyl-ammonium chloride (1112-67-0) → tetra-n-butylammonium tetrachlorogallate(III) (38555-81-6)

Guidance literature:

With hydrogenchloride; In water; Ga was dissolved in aq. HCl, soln. was boiled, excess of ligand was added; collected, dried, recrystd. from CH2Cl2, Et2O was added;

DOI:10.1021/ic50221a015

Reference yield:

tetrabutyl-ammonium chloride (1112-67-0) + Gallium trichloride (13450-90-3) → tetra-n-butylammonium tetrachlorogallate(III) (38555-81-6)

Guidance literature:

In water; aq. soln. of gallium trihalide and N(C4H9)4Cl were mixed; ppt. was filtered, washed with deionised water, recrystd. from ethanol;

DOI:10.1021/ic061871y

Reference yield:

tetrabutyl-ammonium chloride (1112-67-0) + Gallium trichloride (13450-90-3) → tetra-n-butylammonium tetrachlorogallate (38555-81-6)

Guidance literature:

In benzene; components solns. mixing in equimolar proportions, layers sepn., lower layer concn. (vac., 30-35°C) until crystn. onset; crystals filtration off, drying to const. weight at 20°C; elem. anal.;

upstream raw materials:

tetrabutyl-ammonium chloride

Gallium trichloride

gallium

Refernces

• 1、 Miyazaki,Yamazaki,Aimatsu,Enoki,Watanabe,Ogura,Kuwatani,Iyoda. "Crystal structure and physical properties of conducting molecular antiferromagnets with a halogen-substituted donor: (EDO-TTFBr2) 2FeX4 (X = Cl, Br)". . p. 3353 - 3366. Retrieved 2008/10/09.