tert-Butyldioxidanyl

Base Information

• Chemical Name: tert-Butyldioxidanyl
• CAS No.: 3395-62-8
• Molecular Formula: C4H9O2
• Molecular Weight: 89.1143
• DSSTox Substance ID: DTXSID60955527
• Nikkaji Number: J505.685C
• Mol file: 3395-62-8.mol

Synonyms:3395-62-8;tert-Butyldioxidanyl;(Ch3)3co2;DTXSID60955527

Chemical Property of tert-Butyldioxidanyl

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 89.060254526
• Heavy Atom Count: 6
• Complexity: 35.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)O[O]

Technology Process of tert-Butyldioxidanyl

There total 5 articles about tert-Butyldioxidanyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert.-butylhydroperoxide (75-91-2) → methanol (67-56-1) + formaldehyd (50-00-0,30525-89-4,61233-19-0) + methyl tert-butyl peroxide (51392-67-7) + tert-butylperoxyl (3395-62-8) + acetone (67-64-1) + tert-butyl alcohol (75-65-0)

Guidance literature:

With sodium nitrate; air; manganese(III) hydrate; buffer pH 10 (HCO₃^-/CO₃^2-); dihydrogen peroxide; at 30 ℃; Rate constant; Equilibrium constant; Mechanism; var. pH, other reaction partners;

DOI:10.1021/ja00033a030

Reference yield:

tert.-butylhydroperoxide (75-91-2) + cumyloxy radical (16812-36-5) → tert-butylperoxyl (3395-62-8) + 1-methyl-1-phenylethyl alcohol (617-94-7)

Guidance literature:

In tetrachloromethane; at 24.9 ℃; Rate constant; var. solvents;

DOI:10.1021/ja00115a029

Reference yield:

tert.-butylhydroperoxide (75-91-2) + tert-butoxy radical (3141-58-0) → tert-butylperoxyl (3395-62-8) + tert-butyl alcohol (75-65-0)

Guidance literature:

In gas; at 39.9 ℃; Rate constant; at different temperatures;

upstream raw materials:

tert.-butylhydroperoxide

tert-butoxy radical

azo-t-butane

diphenyldisulfane

Downstream raw materials:

tert.-butylhydroperoxide

manganese(III) ion

methanol

formaldehyd

Refernces

• 1、 Avila, David V.,Ingold,Lusztyk,Green,Procopio. "Dramatic solvent effects on the absolute rate constants for abstraction of the hydroxylic hydrogen atom from tert-butyl hydroperoxide and phenol by the cumyloxyl radical. The role of hydrogen bonding". . p. 2929 - 2930. Retrieved 2007/10/02.
• 2、 Arasasingham, Ramesh D.,Jeon, Seungwon,Bruice, Thomas C.. "Dynamics of the reactions of [meso-tetrakis(2,6-dimethyl-3-sulfonatophenyl)porphinato]-manganese(III) hydrate with various alkyl hydroperoxides in aqueous solution. Product studies and comparison of kinetic parameters". . p. 2536 - 2544. Retrieved 2007/10/02.