Amidophosphoric acid bis(4-methylphenyl) ester

Base Information

• Chemical Name: Amidophosphoric acid bis(4-methylphenyl) ester
• CAS No.: 56830-89-8
• Molecular Formula: C14H16NO3P
• Molecular Weight: 277.26
• Mol file: 56830-89-8.mol

Synonyms:Amidophosphoric acid bis(4-methylphenyl) ester;Phosporamidic acid bis(4-methylphenyl) ester

Chemical Property of Amidophosphoric acid bis(4-methylphenyl) ester

Chemical Property:

• PSA: 71.36000
• LogP: 4.52830

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Amidophosphoric acid bis(4-methylphenyl) ester

There total 5 articles about Amidophosphoric acid bis(4-methylphenyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

N-(di-p-cresylphosphinoyl)-O-methylsulphonylhydroxylamine (105077-53-0) + tert-butylamine (75-64-9) → di-p-methylphenyl amidophosphate (56830-89-8) + t-butylammonium salt of di-p-tolyl hydrogen phosphate

Guidance literature:

In dichloromethane; for 72h; Ambient temperature;

Reference yield:

→ tri-p-cresyl phosphate (78-32-0) + di-p-methylphenyl amidophosphate (56830-89-8)

Guidance literature:

With trichlorophosphate; man fuehrt das entstehende Di-p-tolyl-phosphat durch Erwaermen mit PCl₅ in das Chlorid ueber und schuettelt mit konz. Ammoniak;

Reference yield:

dicresyl phosphorochloridate (6630-15-5) → di-p-methylphenyl amidophosphate (56830-89-8)

Guidance literature:

With ammonia; In ethanol; water;

DOI:10.1007/BF00957317

upstream raw materials:

dicresyl phosphorochloridate

N-(di-p-cresylphosphinoyl)-O-methylsulphonylhydroxylamine

tert-butylamine

p-cresol

Downstream raw materials:

Diethyl phosphoramidate

ethylphosphoramidate

Thiophosphorsaeure-di-p-tolylester-isocyanat

C₁₄H₁₄Cl₃NO₃P₂

Refernces

• 1、 Harger, Martin J. P.,Smith, Adrian. "N-Phosphonoyl and N-Phosphoroyl Hydroxylamines: Reactions of their O-Sulphonyl Derivatives with t-Butylamine". . p. 2651 - 2656. Retrieved 2007/10/02.