hydrazine solution anhydrous

Base Information

• Chemical Name: hydrazine solution anhydrous
• CAS No.: 119775-10-9
• Molecular Formula: H₃N₂
• Molecular Weight: 31.0372
• Mol file: 119775-10-9.mol

Synonyms:CCRIS 335; Diamine; HSDB 544; Hydrazine; Hydrazine base; Hydrazine, anhydrous; Hydrazyna; Hydrazyna [Polish]; Levoxine; Nitrogen hydride; Oxytreat 35; RCRA waste number U133; UNII-27RFH0GB4R

Chemical Property of hydrazine solution anhydrous

Chemical Property:

• Melting Point: 1.4℃
• Boiling Point: 113℃
• Flash Point: 52℃
• Density: 1.01
• Water Solubility.: miscible

Purity/Quality:

Safty Information:

• Hazard Codes: T:Toxic;;
• Statements: R10:Flammable.; R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.; R34:Causes burns.; R
• Safety Statements: S45:In case of accident of if you feel unwell, seek medical advice immediately (show the label where possible).; S53:Avoi

MSDS Files:

Useful:

Technology Process of hydrazine solution anhydrous

There total 571 articles about hydrazine solution anhydrous which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

Nitrite → nitrogen (7727-37-9) + ammonia (7664-41-7) + hydroxylamine (7803-49-8) + dinitrogen monoxide (10024-97-2) + hydrazine (302-01-2,78206-91-4,119775-10-9,75013-58-0)

Guidance literature:

In dichloromethane; Electrochem. Process; electrocatalytic redn. at Fe(III)(PP)Cl-modified electrode, pH 2.1, -0.8 V, 1.0 h;

Reference yield: 31.0%

tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex + nitrogen (7727-37-9) → ammonia (7664-41-7) + hydrogen (1333-74-0) + hydrazine (302-01-2,78206-91-4,119775-10-9,75013-58-0)

Guidance literature:

With potassium graphite; C₃₀H₅₁ClNOP₂V; In diethyl ether; at -78 - 20 ℃; for 1.33333h; under 760.051 Torr; Reagent/catalyst; Schlenk technique;

DOI:10.1002/anie.201802310

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + 6-nitro-2,3-dihydrophthalazine-1,4-dione (3682-19-7) → 4-nitrophthalic acid (610-27-5) + hydrazine (302-01-2,78206-91-4,119775-10-9,75013-58-0)

Guidance literature:

at 150 ℃; im Rohr;

upstream raw materials:

1,2-dihydro-[1,2,4,5]tetrazine-3-carboxylic acid

sulfuric acid

hydrogenchloride

ethyl 3-oxo-6-phenyl-2,3,4,5-tetrahydropyridazine-4-carboxylate

Downstream raw materials:

5-benzofuran-2-yl-4-(4-nitro-phenylazo)-1H-pyrazole-3-carboxylic acid ethyl ester

3-(4-methoxyphenyl)-5-phenyl-1H-pyrazole

D-glucosone

1,2-bis(3-bromophenyl)hydrazine

Refernces

• 1、 Wenner, R. R.,Beckman, A. O.. "". . p. 2787. Retrieved 1932.
• 2、 Yuki, Masahiro,Miyake, Yoshihiro,Nishibayashi, Yoshiaki,Wakiji, Issei,Hidai, Masanobu. "Synthesis and reactivity of tungsten- and molybdenum-dinitrogen complexes bearing ferrocenyldiphosphines toward protonolysis". . p. 3947 - 3953. Retrieved 2008.
• 3、 Clarke,Edge,Johnson,Land,Navaratnam,Truscott. "Direct observation of NH2 reactions with oxygen, amino acids, and melanins". . p. 1234 - 1237. Retrieved 2008.
• 4、 Xiong, Wei,Guo, Zheng,Zhao, Shijun,Wang, Qian,Xu, Qiyong,Wang, Xinwei. "Facile, cost-effective plasma synthesis of self-supportive FeS: X on Fe foam for efficient electrochemical reduction of N2 under ambient conditions". . p. 19977 - 19983. Retrieved 2019.
• 5、 Koizumi,Yoneyama,Tamura. "ELECTROCHEMICAL FIXATION OF MOLECULAR NITROGEN ON p-TYPE GALLIUM PHOSPHIDE PHOTOCATHODE.". . p. 1682 - 1687. Retrieved 1981.
• 6、 Saha, Paramita,Amanullah, Sk,Dey, Abhishek. "Electrocatalytic Reduction of Nitrogen to Hydrazine Using a Trinuclear Nickel Complex". . p. 17312 - 17317. Retrieved 2020.
• 7、 Bae, Dae Young,Lee, Gunhee,Lee, Eunsung. "Fixation of Dinitrogen at an Asymmetric Binuclear Titanium Complex". . p. 12813 - 12822. Retrieved 2021.
• 8、 Gao, Yafei,Li, Guangyu,Deng, Liang. "Bis(dinitrogen)cobalt(-1) Complexes with NHC Ligation: Synthesis, Characterization, and Their Dinitrogen Functionalization Reactions Affording Side-on Bound Diazene Complexes". . p. 2239 - 2250. Retrieved 2018.
• 9、 Han, Jingrui,Ji, Xuqiang,Ren, Xiang,Cui, Guanwei,Li, Lei,Xie, Fengyu,Wang, Hui,Li, Baihai,Sun, Xuping. "MoO3 nanosheets for efficient electrocatalytic N2 fixation to NH3". . p. 12974 - 12977. Retrieved 2018.
• 10、 Beckman, A. O.,Dickinson, R. G.. "". . p. 124. Retrieved 1930.