4-Fluorophenoxy

Base Information

• Chemical Name: 4-Fluorophenoxy
• CAS No.: 2145-21-3
• Molecular Formula: C6H4FO
• Molecular Weight: 111.096
• DSSTox Substance ID: DTXSID00175727
• Nikkaji Number: J520.010E
• Mol file: 2145-21-3.mol

Synonyms:4-Fluorophenoxy;2145-21-3;4-F-phenoxy;DTXSID00175727

Chemical Property of 4-Fluorophenoxy

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 111.024617909
• Heavy Atom Count: 8
• Complexity: 66.9

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=CC=C1[O])F

Technology Process of 4-Fluorophenoxy

There total 8 articles about 4-Fluorophenoxy which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-Fluorophenol (371-41-5) + CH3I(1+)*CHCl3*Cl(1-) → chloroform (67-66-3,8013-54-5) + p-fluorophenoxyl radical (2145-21-3) + methyl iodide (74-88-4)

Guidance literature:

In chloroform; at 22 ℃; Rate constant; multistep reaction;

DOI:10.1021/j100164a045

Reference yield:

4-Fluorophenol (371-41-5) + CCl4*CH3I(1+)*Cl(1-) → tetrachloromethane (56-23-5) + p-fluorophenoxyl radical (2145-21-3) + methyl iodide (74-88-4)

Guidance literature:

In tetrachloromethane; at 22 ℃; Rate constant; multistep reaction;

DOI:10.1021/j100164a045

Reference yield:

4-Fluorophenol (371-41-5) + CH3I(1+)*CH2Cl2*Cl(1-) → dichloromethane (75-09-2) + p-fluorophenoxyl radical (2145-21-3) + methyl iodide (74-88-4)

Guidance literature:

In dichloromethane; at 22 ℃; Rate constant; multistep reaction;

DOI:10.1021/j100164a045

upstream raw materials:

4-Fluorophenol

perfluorobutylperoxyl radical

4-iodophenoxyl radical

4-fluorophenolate anion

Downstream raw materials:

chlorine dioxide

4-fluorophenolate anion

4-iodophenoxyl radical

Refernces

• 1、 Nahor, G. S.,Neta, P.,Alfassi, Z. B.. "Perfluorobutylperoxyl Radical as an Oxidant in Various Solvents". . p. 4419 - 4422. Retrieved 2007/10/02.
• 2、 Lind,Shen,Eriksen,Merényi. "The one-electron reduction potential of 4-substituted phenoxyl radicals in water". . p. 479 - 482. Retrieved 2007/10/02.