meso-Tetra (p-bromophenyl) porphine

Base Information

• Chemical Name: meso-Tetra (p-bromophenyl) porphine
• CAS No.: 29162-73-0
• Molecular Formula: C44H26Br4N4
• Molecular Weight: 930.333
• Hs Code.: 29339900
• Mol file: 29162-73-0.mol

Synonyms:5,10,15,20-tetrakis(4-bromophenyl)-21,22-dihydroporphyrin;Tetrakis(4-bromophenyl)porphyrin;

Chemical Property of meso-Tetra (p-bromophenyl) porphine

Chemical Property:

• Melting Point: 170 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 56.30000
• Density: 1.675g/cm³
• LogP: 9.91620
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: Chloroform (Slightly), Methanol (Slightly)

Purity/Quality:

98%,99%, ^*data from raw suppliers

meso-Tetra(p-Bromophenyl)Porphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: meso-Tetra (p-Bromophenyl) Porphine is a synthetic halogenated porphyrin.

Technology Process of meso-Tetra (p-bromophenyl) porphine

There total 20 articles about meso-Tetra (p-bromophenyl) porphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pyrrole (109-97-7,30604-81-0) + 4-bromo-benzaldehyde (1122-91-4) → 5,10,15,20-tetrakis(p-bromophenyl)porphyrin (29162-73-0)

Guidance literature:

With hydrogenchloride; In water; at 20 ℃; for 2h;

DOI:10.1002/chem.201901315

Reference yield: 78.0%

pyrrole (109-97-7,30604-81-0) + 4-bromo-benzaldehyde (1122-91-4) → 5,10,15,20-tetrakis(p-bromophenyl)porphyrin (29162-73-0)

Guidance literature:

With propionic acid; In dichloromethane; for 0.333333h; Reagent/catalyst; Sealed tube; Microwave irradiation; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.molstruc.2019.127139

Reference yield: 15.0%

2-[(4-bromophenyl)hydroxymethyl]-5-[(2-allyloxy-5-bromophenyl)hydroxymethyl]thiophene + pyrrole (109-97-7,30604-81-0) + 4-bromo-benzaldehyde (1122-91-4) → 5-(2-allyloxy-5-bromophenyl)-10,15,20-tri(4-bromophenyl)-21-thiaporphyrin + 5,10,15,20-tetrakis(p-bromophenyl)porphyrin (29162-73-0)

Guidance literature:

2-[(4-bromophenyl)hydroxymethyl]-5-[(2-allyloxy-5-bromophenyl)hydroxymethyl]thiophene; pyrrole; 4-bromo-benzaldehyde; With boron trifluoride diethyl etherate; In dichloromethane; for 3h;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane;

DOI:10.1016/j.tet.2005.01.037

upstream raw materials:

pyrrole

4-bromo-benzaldehyde

4-methoxy-benzaldehyde

tetrakis(4-aminophenyl)porphyrin

Downstream raw materials:

(5,10,15,20-tetrakis(4-bromophenyl)porphyrinato)zinc(II)

[5,10,15,20-tetrakis(p-bromophenyl)porphyrinato]iron(III) chloride

Refernces

• 1、 Rhauderwiek, Timo,Wolkersd?rfer, Konrad,?ien-?Degaard, Sigurd,Lillerud, Karl-Petter,Wark, Michael,Stock, Norbert. "Crystalline and permanently porous porphyrin-based metal tetraphosphonates". . p. 389 - 392. Retrieved 2018.
• 2、 Matamala-Cea, Edison,Valenzuela-Godoy, Fabián,González, Déborah,Arancibia, Rodrigo,Dorcet, Vincent,Hamon, Jean-René,Novoa, Néstor. "Efficient preparation of 5,10,15,20-tetrakis(4-bromophenyl)porphyrin. Microwave assisted v/s conventional synthetic method, X-ray and hirshfeld surface structural analysis". . . Retrieved 2020.
• 3、 Shi, Kaixiang,Song, Ningning,Zou, Yongcun,Zhu, Shiyang,Tan, Haiwei,Tian, Ye,Zhang, Bo,Yao, Hongyan,Guan, Shaowei. "Porphyrin-based porous polyimides: Synthesis, porous structure, carbon dioxide adsorption". . p. 160 - 166. Retrieved 2019.
• 4、 Amuhaya, Edith K.,Derese, Solomon,Lanterna, Anabel E.,Mack, John,Nyokong, Tebello,Otieno, Sebastian,Scaiano, Juan C.. "Solar driven photocatalytic activity of porphyrin sensitized TiO2: Experimental and computational studies". . . Retrieved 2021.
• 5、 Yadav, Omprakash,Varshney, Atul,Kumar, Anil. "Manganese(III) mediated synthesis of A2B Mn(III) corroles: A new general and green synthetic approach and characterization". . p. 168 - 171. Retrieved 2017.
• 6、 Pukhovskaya,Ivanova,Kiselev,Fomina,Syrbu. "Synthesis, structure and basic properties of 5,10,15,20-tetrakis[4′-(benzoxazole-2-yl)phenyl]-21,23-dithiaporphyrin". . . Retrieved 2021.
• 7、 Amiri, Nesrine,Ben Taheur, Fadia,Chevreux, Sylviane,Dorcet, Vincent,Lemercier, Gilles,Nasri, Habib,Rodrigues, Carine Machado. "Syntheses, crystal structures, photo-physical properties, antioxidant and antifungal activities of Mg(II) 4,4′-bipyridine and Mg(II) pyrazine complexes of the 5,10,15,20 tetrakis(4–bromophenyl)porphyrin". . . Retrieved 2021.
• 8、 Erkan, Sultan,K?rp?k, Hilal,Kose, Muhammet. "A new 3-substituted BODIPY dye: Synthesis, crystal structure, photophysical, non-linear optic and OLED properties". . . Retrieved 2021/12/20.
• 9、 Dong, Xinyi,Fang, Xianying,Fu, Bo,Liang, Xu,Xu, Haijun,Yu, Xiaoxiao,Zhang, Zhen,Zhu, Weihua. "C2 symmetric borneol-porphyrin hybrids: Synthesis, characterization, electronic structure and their anti-cancer behaviors". . . Retrieved 2020/09/17.