1-Bromo-4-dibenzothiophenamine

Base Information

• Chemical Name: 1-Bromo-4-dibenzothiophenamine
• CAS No.: 854392-97-5
• Molecular Formula: C₁₂H₈BrNS
• Molecular Weight: 278.172
• Mol file: 854392-97-5.mol

Synonyms:1-Bromo-4-dibenzothiophenamine

Chemical Property of 1-Bromo-4-dibenzothiophenamine

Chemical Property:

• Melting Point: 156℃
• PSA: 54.26000
• LogP: 4.98040

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Bromo-4-dibenzothiophenamine

There total 7 articles about 1-Bromo-4-dibenzothiophenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dibenzothiophene (132-65-0) → 1-bromo-4-dibenzothiopheneamine (854392-97-5)

Guidance literature:

Multi-step reaction with 5 steps

1: butyl lithium; diethyl ether / Behandeln der Reaktionsloesung mit Brom-Dampf in Stickstoff-Strom

2: copper (I)-bromide; aqueous ammonia / 220 °C

3: benzene

4: bromine; acetic acid

5: ethanol; aqueous hydrochloric acid

With hydrogenchloride; ammonium hydroxide; n-butyllithium; diethyl ether; ethanol; bromine; acetic acid; copper(I) bromide; benzene;

DOI:10.1021/jo01219a003

Reference yield:

biphenyl (92-52-4,1594-86-1) → 1-bromo-4-dibenzothiopheneamine (854392-97-5)

Guidance literature:

Multi-step reaction with 6 steps

1: aluminium chloride; sulfur

2: butyl lithium; diethyl ether / Behandeln der Reaktionsloesung mit Brom-Dampf in Stickstoff-Strom

3: copper (I)-bromide; aqueous ammonia / 220 °C

4: benzene

5: bromine; acetic acid

6: ethanol; aqueous hydrochloric acid

With hydrogenchloride; ammonium hydroxide; n-butyllithium; aluminium trichloride; diethyl ether; ethanol; bromine; sulfur; acetic acid; copper(I) bromide; benzene;

DOI:10.1021/jo01219a003

Reference yield:

1-bromo-N-4-dibenzothiophenylacetamide (854392-93-1) → 1-bromo-4-dibenzothiopheneamine (854392-97-5)

Guidance literature:

With hydrogenchloride; ethanol;

DOI:10.1021/jo01219a003

upstream raw materials:

1-bromo-N-4-dibenzothiophenylacetamide

dibenzothiophene

4-bromodibenzothiophene

4-hydroxydibenzothiophene

Downstream raw materials:

1-bromodibenzo[b,d]thiophene