Palladium, diamminedichloro-, cis-

Base Information

• Chemical Name: Palladium, diamminedichloro-, cis-
• CAS No.: 13782-33-7
• Molecular Formula: Cl₂H₆N₂Pd
• Molecular Weight: 211.387
• Hs Code.: 2843900090
• Mol file: 13782-33-7.mol

Synonyms:chloropalladosamine

Chemical Property of Palladium, diamminedichloro-, cis-

Chemical Property:

• Appearance/Colour: yellow powder
• PSA: 6.48000
• Density: 2.5 g/mL at 25 °C(lit.)
• LogP: 2.02680
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 209.89428
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

trans-Dichlorodiammine palladium(II), 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-36/37/38
• Safety Statements: 22-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: N.N.[Cl-].[Cl-].[Pd+2]

Technology Process of Palladium, diamminedichloro-, cis-

There total 54 articles about Palladium, diamminedichloro-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ammonium tetrachloropalladate(II) → trans-diamminedichloride palladium(II) (13782-33-7,14323-43-4,15684-18-1)

Guidance literature:

In neat (no solvent); byproducts: HCl; isothermal decompn. at 216°C; elem. anal.;

Reference yield: 96.0%

ammonia (7664-41-7) + palladium dichloride → diamminedichloropalladium(II) (14323-43-4,15684-18-1,13782-33-7)

Guidance literature:

In hydrogenchloride; PdCl2 was dissolved in 0.2 M HCl, 25 % aq. NH3 was added at 50 °C, stirring for 2 h; soln. was ice-cooled, concd. HCl was added, solid was filtered, washed several times with water (ice-cooled), dried;

Reference yield: 90.0%

chloroauric acid + tetraamminepalladium(II) nitrate → diamminedichloropalladium(II) (14323-43-4,15684-18-1,13782-33-7) + tetraamminepalladium(II) tetrachloroaurate (III)

Guidance literature:

In water; HAuCl4 added to satd. aq. soln. of Pd(NH3)4(NO3)2; ppt. filtered off (vac.); washed (min. amt. of H2O, EtOH); dried (air); elem. anal.;

DOI:10.1134/S0036023607030138

upstream raw materials:

tetramminepalladium(II) chloride

hydrogenchloride

ammonia

palladium

Downstream raw materials:

palladium

tetrachloro diammine palladium (IV)

trans dinitrato diammine palladium (II)

trans-diamminedichloropalladium(II)

Refernces

• 1、 Taaltin, Nevin,?ztürk, Sadullah,Kilin, Necmettin,Yüzer, Hayrettin,?ztürk, Zafer Ziya. "Fabrication of Pd-Fe nanowires with a high aspect ratio by AAO template-assisted electrodeposition". . p. 3894 - 3898. Retrieved 2011.
• 2、 Mitkina, Tatiana V.,Naumov, Dmitriy Yu.,Gerasko, Olga A.,Fedin, Vladimir P.. "Crystal structure and chemical oxidation of the palladium(II) cyclam complex within the cavity of cucurbit[8]uril". . p. 4387 - 4391. Retrieved 2011/02/28.