bicyclo[4.1.0]hept-3-ene

Base Information

• Chemical Name: bicyclo[4.1.0]hept-3-ene
• CAS No.: 84194-54-7
• Molecular Formula: C7H10
• Molecular Weight: 94.1564
• Mol file: 84194-54-7.mol

Synonyms:

Chemical Property of bicyclo[4.1.0]hept-3-ene

Chemical Property:

• Vapor Pressure: 28.1mmHg at 25°C
• Boiling Point: 110.3°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.955g/cm³
• LogP: 1.97250

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bicyclo[4.1.0]hept-3-ene

There total 1 articles about bicyclo[4.1.0]hept-3-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

3-chloro-4-thia-trans-bicyclo<5.1.0>octane 4,4-dioxide (84194-53-6) → trans-bicyclo<4.1.0>hept-3-ene (84194-54-7)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; for 0.5h; Ambient temperature;

DOI:10.1021/ja00189a046

Reference yield: 51.0%

trans-bicyclo<4.1.0>hept-3-ene (84194-54-7) → 2,5-dihydrotoluene (4313-57-9) + 4-Methylen-1-cyclohexen (13407-18-6) + cis-bicyclo<4.1.0>hept-3-ene (88090-52-2)

Guidance literature:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium; Ambient temperature;

DOI:10.1016/S0040-4039(00)86005-0

Reference yield:

trans-bicyclo<4.1.0>hept-3-ene (84194-54-7) → 2,5-dihydrotoluene (4313-57-9) + cis-bicyclo<4.1.0>hept-3-ene (88090-52-2)

Guidance literature:

With di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium; In benzene-d6; Ambient temperature;

DOI:10.1016/S0040-4039(00)80613-9

upstream raw materials:

3-chloro-4-thia-trans-bicyclo<5.1.0>octane 4,4-dioxide

Downstream raw materials:

2,5-dihydrotoluene

4-Methylen-1-cyclohexen

cis-bicyclo<4.1.0>hept-3-ene

trans-bicyclo<4.1.0>heptan-3-ol

Refernces