Benzenamine, 5-ethyl-2-methoxy-

Base Information

• Chemical Name: Benzenamine, 5-ethyl-2-methoxy-
• CAS No.: 67291-61-6
• Molecular Formula: C9H13NO
• Molecular Weight: 151.208
• Mol file: 67291-61-6.mol

Synonyms:Benzenamine, 5-ethyl-2-methoxy-;5-ethyl-2-Methoxyaniline

Chemical Property of Benzenamine, 5-ethyl-2-methoxy-

Chemical Property:

• PSA: 35.25000
• LogP: 2.42100
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature

Purity/Quality:

99%min ^*data from raw suppliers

5-Ethyl-2-methoxyaniline 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenamine, 5-ethyl-2-methoxy-

There total 5 articles about Benzenamine, 5-ethyl-2-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-nitro-4-vinyl-anisole (7403-69-2) → 5-ethyl-2-methoxy-aniline (67291-61-6)

Guidance literature:

With hydrogen; palladium 10% on activated carbon; In ethyl acetate; at 20 ℃;

Reference yield:

4-methoxy-3-nitrobenzaldehyde (31680-08-7) → 5-ethyl-2-methoxy-aniline (67291-61-6)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydride / tetrahydrofuran; mineral oil / 1 h / Reflux

2: hydrogen / palladium 10% on activated carbon / ethyl acetate / 20 °C

With hydrogen; sodium hydride; palladium 10% on activated carbon; In tetrahydrofuran; ethyl acetate; mineral oil;

Reference yield:

p-ethylanisole (1515-95-3) → 5-ethyl-2-methoxy-aniline (67291-61-6)

Guidance literature:

Multistep reaction; (i) Ac₂O, HNO₃, (ii) H₂, Raney-Ni;

DOI:10.1021/ja00715a021

upstream raw materials:

4-ethyl-2-nitro-anisole

p-ethylanisole

4-methoxy-3-nitrobenzaldehyde

2-nitro-4-vinyl-anisole

Downstream raw materials:

N-Diaethylaminoacetyl-2-methoxy-5-aethyl-anilin

N-(5-ethyl-2-methoxy-phenyl)-2-morpholin-4-yl-acetamide

Refernces

• 1、 -. "Reactive yellow dye having both monochlorotriazinyl and vinylsulfone type reactive groups". . . Retrieved 2008/06/13.