1,1,2-Trifluoro-2-chloro-3-methyl-3-vinylcyclobutane

Base Information

• Chemical Name: 1,1,2-Trifluoro-2-chloro-3-methyl-3-vinylcyclobutane
• CAS No.: 4265-28-5
• Molecular Formula: C7H8ClF3
• Molecular Weight: 184.589
• Hs Code.: 2903890090
• DSSTox Substance ID: DTXSID80380372
• Mol file: 4265-28-5.mol

Synonyms:1,1,2-Trifluoro-2-chloro-3-methyl-3-vinylcyclobutane;4265-28-5;2-chloro-1-ethenyl-2,3,3-trifluoro-1-methylcyclobutane;2-Chloro-3-methyl-1,1,2-trifluoro-3-vinylcyclobutane;2-chloro-1,1,2-trifluoro-3-methyl-3-vinylcyclobutane;SCHEMBL9861836;DTXSID80380372;MFCD00039438;AKOS006230192;FT-0635196;1-methyl-1-vinyl-2-chloro-2,3,3-trifluorocyclobutane

Chemical Property of 1,1,2-Trifluoro-2-chloro-3-methyl-3-vinylcyclobutane

Chemical Property:

• Vapor Pressure: 14.3mmHg at 25°C
• Boiling Point: 126.1°C at 760 mmHg
• Flash Point: 37.2°C
• PSA: 0.00000
• Density: 1.23g/cm³
• LogP: 3.12230
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 184.0266624
• Heavy Atom Count: 11
• Complexity: 204

Purity/Quality:

98%min ^*data from raw suppliers

1,1,2-Trifluoro-2-chloro-3-methyl-3-vinylcyclobutane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,F
• Hazard Codes: Xi,F

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(CC(C1(F)Cl)(F)F)C=C

Technology Process of 1,1,2-Trifluoro-2-chloro-3-methyl-3-vinylcyclobutane

There total 2 articles about 1,1,2-Trifluoro-2-chloro-3-methyl-3-vinylcyclobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Chlorotrifluoroethylene (79-38-9,9036-80-0) + isoprene (78-79-5,9003-31-0) → 2-chloro-1,1,2-trifluoro-3-isopropenylcyclobutane (116850-27-2) + 2-chloro-1,1,2-trifluoro-3-methyl-3-vinylcyclobutane (4265-28-5)

Guidance literature:

DOI:10.1021/ja00782a025

Reference yield:

→ 2-chloro-1,1,2-trifluoro-3-methyl-3-vinylcyclobutane (4265-28-5)

Guidance literature:

3-Methylbuta-1,2-dien, Chlortrifluorethylen;

DOI:10.1039/j39710000391

Reference yield: 51.0%

2-chloro-1,1,2-trifluoro-3-methyl-3-vinylcyclobutane (4265-28-5) → 3,4-difluorotoluene (2927-34-6) + 4-chloro-4,5,5-trifluoro-1-methylcyclohex-1-ene

Guidance literature:

at 470 ℃; for 1h; Temperature; Inert atmosphere; Flow reactor;

DOI:10.1007/s11172-020-2724-8

upstream raw materials:

Chlorotrifluoroethylene

isoprene

Downstream raw materials:

3,4-difluorotoluene

1-chloro-2-fluoro-4-methylbenzene