BCC-36

Base Information

• Chemical Name: BCC-36
• CAS No.: 211685-96-0
• Molecular Formula: C42H27N3
• Molecular Weight: 573.696
• Mol file: 211685-96-0.mol

Synonyms:3,6-Bis(N-carbazolyl)-N-phenylcarbazole;9′-Phenyl-9,3′:6′,9′′-ter-9H-carbazole;BCC-36;N-Phenyl-3,6-tricarbazolylcarbazole

Chemical Property of BCC-36

Chemical Property:

• Melting Point: 281-286°C
• PSA: 14.79000
• Density: 1.26±0.1 g/cm3(Predicted)
• LogP: 10.97790

Purity/Quality:

98.5% ^*data from raw suppliers

3,6-Bis(N-carbazolyl)-N-phenylcarbazole 99% (HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Host materials for efficient solution-processed blue phosphorescent devicesDevice-1: ITO/PEDOT:PSS/BCC-27:FIrpic (10 wt%)/TAZ/Cs2CO3/AlPerformance: Deep Blue, Turn on Voltage: 3.9 V, Max Lum: 19,200 Cd/m2, EQE: 9.7%Device-2: ITO/PEDOT:PSS/BCC-27:FIr6 (10 wt%)/TAZ/Cs2CO3/AlPerformance: Deep Blue, Turn on Voltage: 5.0 V, Max Lum: 12,300 Cd/m2, EQE: 4.1%

Technology Process of BCC-36

There total 7 articles about BCC-36 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + 3,6-diiodo-9-phenyl-9H-carbazole (57103-21-6) → 3,6-di(9H-carbazol-9-yl)-9-phenyl-9H-carbazole (211685-96-0)

Guidance literature:

With copper; potassium carbonate; 18-crown-6 ether; In 1,2-dichloro-benzene; at 178 ℃; for 18h; Inert atmosphere;

Reference yield: 85.0%

→ 3,6-di(9H-carbazol-9-yl)-9-phenyl-9H-carbazole (211685-96-0)

Guidance literature:

Reference yield: 82.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + 3,6-dibromo-9-phenyl-9H-carbazole (57103-20-5) → 3,6-di(9H-carbazol-9-yl)-9-phenyl-9H-carbazole (211685-96-0)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; sodium t-butanolate; In toluene; at 110 ℃; for 24h;

DOI:10.1039/c0jm03365k

upstream raw materials:

iodobenzene

3,6-di(N-carbazolyl)carbazole

N-phenylcarbazole

9H-carbazole

Refernces

• 1、 -. "N-PHENYL TRISCARBAZOLE". . . Retrieved 2012/03/26.
• 2、 Jiang, Wei,Duan, Lian,Qiao, Juan,Dong, Guifang,Zhang, Deqiang,Wang, Liduo,Qiu, Yong. "High-triplet-energy tri-carbazole derivatives as host materials for efficient solution-processed blue phosphorescent devices". . p. 4918 - 4926. Retrieved 2011/10/12.