D-allo-Inositol hexaacetate

Base Information

• Chemical Name: D-allo-Inositol hexaacetate
• CAS No.: 29267-04-7
• Molecular Formula: C18H24O12
• Molecular Weight: 432.381
• Hs Code.: 2915900090
• Mol file: 29267-04-7.mol

Synonyms:allo-Inositol hexaacetate;D-allo-Inositol hexaacetate

Chemical Property of D-allo-Inositol hexaacetate

Chemical Property:

• PSA: 157.80000
• LogP: -0.40980

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of D-allo-Inositol hexaacetate

There total 22 articles about D-allo-Inositol hexaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

allo-inositol (643-10-7) + acetic anhydride (108-24-7) → hexa-O-acetyl allo-inositol (29267-04-7)

Guidance literature:

With pyridine; at 80 ℃; for 8h;

DOI:10.1002/ejoc.201000009

Reference yield: 87.0%

2,6-di-O-benzyl-1D-allo-inositol (1214834-30-6) + acetic anhydride (108-24-7) → hexa-O-acetyl allo-inositol (29267-04-7)

Guidance literature:

2,6-di-O-benzyl-1D-allo-inositol; With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 7h; under 760.051 Torr;

acetic anhydride; With pyridine; at 20 ℃; for 24h;

DOI:10.3762/bjoc.12.227

Reference yield:

acetic anhydride (108-24-7) + deseryladenomycin (76235-11-5) → pentaacetyl L-gulosamine (3006-60-8,4539-83-7,6730-10-5,7772-79-4,7784-54-5,10385-50-9,14086-90-9,26151-16-6,76375-60-5,76375-61-6,95341-98-3,95341-99-4,134451-91-5,134451-96-0,136982-81-5,145375-11-7,148347-15-3) + hexaacetyl (-)-chiro-inositol (1254-38-2,18779-57-2,20097-40-9,20108-52-5,20108-67-2,20108-71-8,29267-03-6,29267-04-7,29307-62-8,70878-34-1,100679-00-3) + nonaacetyl adenobiosamine (76250-03-8)

Guidance literature:

With hydrogen cation; Multistep reaction; 2.) pyridine;

DOI:10.1016/S0040-4039(00)77445-4

upstream raw materials:

allo-inositol

acetic anhydride

cis-1,2-dihydrocatechol

benzene

Downstream raw materials:

allo-inositol

Refernces

• 1、 D'Andrea, Felicia,Catelani, Giorgio,Guazzelli, Lorenzo,Pistarà, Venerando. "Useful access to enantiomerically pure protected inositols from carbohydrates: The aldohexos-5-uloses route". supporting information. p. 2343 - 2350. Retrieved 2016/11/17.
• 2、 Lee, Yong Joo,Lee, Kyunghoon,Jung, Sea Ill,Jeon, Heung Bae,Kim, Kwan Soo. "Synthesis of enantiopure cyclitols from (±)-3-bromocyclohexene mediated by intramolecular oxyselenenylation employing (S,S)-hydrobenzoin and (S)-mandelic acid as chiral sources". . p. 1987 - 2001. Retrieved 2007/10/03.