Cyano radical

Base Information

• Chemical Name: Cyano radical
• CAS No.: 2074-87-5
• Molecular Formula: CN
• Molecular Weight: 26.0177
• Nikkaji Number: J597.077F,J2.229.203J
• Wikipedia: Cyano_radical
• Mol file: 2074-87-5.mol

Synonyms:Cyano radical;nitridocarbon(.);CHEBI:29306;CN(.);(CN)(.)

Chemical Property of Cyano radical

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 23.79000
• Density: g/cm³
• LogP: 0.01678
• XLogP3: 0.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 26.003074004
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C]#N

Technology Process of Cyano radical

There total 49 articles about Cyano radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

carbonyl cyanide (1115-12-4) → carbon nitride (2074-87-5) + ethanedinitrile (460-19-5,25215-76-3) + carbon monoxide (201230-82-2) + cyanoxoomethyl radical (145588-76-7,160727-65-1)

Guidance literature:

In gaseous matrix; Irradiation (UV/VIS); 2% CO(CN)2 in 350 mbar He expansion through piezoelectrically actuated valve providing molecular beam pulses of 100 μs, photodissociation at193 nm using ArF excimer laser (20 Hz, laser fluence 10-100 mJ/cm**2);

DOI:10.1063/1.479376

Reference yield:

carbon suboxide (504-64-3) + nitrogen(II) oxide (10102-43-9) → carbon nitride (2074-87-5) + isocyanate radical (22400-26-6) + carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (201230-82-2) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With SF₆; Xe; In neat (no solvent, gas phase); Irradiation (UV/VIS); further products, 266-nm photolysis, 0.1-0.5 Torr C3O2 in the presence of 0-0.8 Torr NO, 1 Torr SF6, and 1.00 Torr Xe at 298-573 K; not isolated, detected by IR; Kinetics;

DOI:10.1021/jp0304125

Reference yield:

cyanonitrene (1884-64-6,2669-76-3) + nitrogen(II) oxide (10102-43-9) → carbon nitride (2074-87-5) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In neat (no solvent, gas phase); kinetics of NCN + NO react. was studied at pressure 30 mbar-50 bar and temps. 251-487 K in flow of He; LIF; Kinetics;

DOI:10.1021/jp303069g

upstream raw materials:

methylene

thiocyanic acid ; manganese (II)-compound

silver(I) cyanide

hydrogen cyanide

Downstream raw materials:

paracetaldehyde

N,N''-dibenzyl-oxalamidine

acetonitrile

propiononitrile

Refernces

• 1、 Robertson, N. C.,Pease, R. N.. "". . p. 1880 - 1886. Retrieved 1942.
• 2、 Blanch, Rodney J.,McCluskey, Adam. "XCN (X=Cl, Br and I): a novel source of isocyanogen". . p. 116 - 120. Retrieved 1995.
• 3、 Arppe, Teemu,Khriachtchev, Leonid,Lignell, Antti,Domanskaya, Alexandra V.,Raesaenen, Markku. "Halogenated xenon cyanides ClXeCN, ClXeNC, and BrXeCN". . p. 4398 - 4402. Retrieved 2012/05/31.
• 4、 McGivern, W. Sean,North, Simon W.. "Treatment of the K-quantum number in unimolecular reaction theory: Insights from product correlations". . p. 14472 - 14477. Retrieved 2007/10/03.