1-Bromoethyl ethyl carbonate

Base Information

• Chemical Name: 1-Bromoethyl ethyl carbonate
• CAS No.: 89766-09-6
• Molecular Formula: C5H9 Br O3
• Molecular Weight: 197.029
• Hs Code.: 2920909090
• European Community (EC) Number: 289-520-9
• DSSTox Substance ID: DTXSID801008962
• Nikkaji Number: J348.606K
• Mol file: 89766-09-6.mol

Synonyms:1-Bromoethyl ethyl carbonate;89766-09-6;EINECS 289-520-9;ethyl alpha-bromoethyl carbonate;SCHEMBL6564563;RKRZYVQFKUXDEZ-UHFFFAOYSA-N;DTXSID801008962;1-ethoxycarbonyloxy-1-ethyl bromide;AKOS006312883;carbonic acid 1-bromoethyl ethyl ester;Carbonic acid (1-bromoethyl)ethyl ester

Chemical Property of 1-Bromoethyl ethyl carbonate

Chemical Property:

• Vapor Pressure: 2.02mmHg at 25°C
• Boiling Point: 163.9°C at 760 mmHg
• Flash Point: 52.9°C
• PSA: 35.53000
• Density: 1.465g/cm³
• LogP: 1.90040
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 195.97351
• Heavy Atom Count: 9
• Complexity: 94.2

Purity/Quality:

99% ^*data from raw suppliers

1-BROMOETHYL ETHYL CARBONATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)OC(C)Br

Technology Process of 1-Bromoethyl ethyl carbonate

There total 11 articles about 1-Bromoethyl ethyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

vinyl ethyl carbonate (7570-06-1) → 1-ethoxycarbonyloxyethyl bromide (89766-09-6)

Guidance literature:

Reference yield: 76.0%

1-Chloroethyl ethyl carbonate (50893-36-2) → 1-ethoxycarbonyloxyethyl bromide (89766-09-6)

Guidance literature:

With lithium bromide; In dichloromethane; water; cetyltrimethylammonim bromide;

Reference yield: 70.0%

Diethyl carbonate (105-58-8,76619-83-5) → 1-ethoxycarbonyloxyethyl bromide (89766-09-6)

Guidance literature:

With bromine; sodium hydrogencarbonate;

upstream raw materials:

1-Chloroethyl ethyl carbonate

Carbonic acid ethyl ester 1-phenylsulfanyl-ethyl ester

dichloromethane

ethylene dibromide

Downstream raw materials:

bacampicillin Hydrochloride

Boc-Tyr(COMe)-D-MetO-Phe-MeβAla-OCH(Me)OCOOEt

Boc-Tyr-D-MetO-Phe-MeβAla-OCH(Me)OCOOEt

Refernces

• 1、 -. "Process for the manufacture of 1-bromoalkyl hydrocarbyl carbonates". . . Retrieved 2008/06/13.
• 2、 -. "Ethoxycarbonyloxy ethyl esters of non-steroidal anti-inflammatory carboxylic acids and pharmaceutical compositions thereof". . . Retrieved 2008/06/13.