tetraethylammonium hydridotetracarbonylferrate

Base Information

• Chemical Name: tetraethylammonium hydridotetracarbonylferrate
• CAS No.: 25879-01-0
• Molecular Formula: C12H21FeNO4
• Molecular Weight: 299.15
• Mol file: 25879-01-0.mol

Synonyms:tetraethylammonium hydridotetracarbonylferrate

Chemical Property of tetraethylammonium hydridotetracarbonylferrate

Chemical Property:

• PSA: 0.00000
• LogP: 1.52440

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tetraethylammonium hydridotetracarbonylferrate

There total 4 articles about tetraethylammonium hydridotetracarbonylferrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

methanol (67-56-1) + iron pentacarbonyl (13463-40-6,71564-23-3,37220-42-1) + tetraethylammonium bromide (71-91-0) → {Et4N}{(H)tetracarbonyl iron} (25879-01-0)

Guidance literature:

With potassium hydroxide; In water; using Schlenk techniques; dissolving of KOH in MeOH in ice bath, addn. of Fe(CO)5 by syringe, stirring for 30 min, warming to room temp., removal of solvent under vac., dissolving in H2O, addn. of aq. soln. of (Et4N)Br under stirring; pptn., filtration, washing with water, drying under vac.;

DOI:10.1021/om020548+

Reference yield:

iron pentacarbonyl (13463-40-6,71564-23-3,37220-42-1) + 2N(C2H5)4(1+)*HTa(CO)5(2-)=(N(C2H5)4)2HTa(CO)5 → {Et4N}{(H)tetracarbonyl iron} (25879-01-0) + Ta(CO)5(C4H8O)(1-)*N(C2H5)4(1+)=Ta(CO)5(C4H8O)N(C2H5)4 + Fe(CO)4CHO(1-)*N(C2H5)4(1+)=Fe(CO)4CHON(C2H5)4

Guidance literature:

In tetrahydrofuran; at -50°C;

DOI:10.1021/ja00329a070

Reference yield:

iron pentacarbonyl (13463-40-6,71564-23-3,37220-42-1) + 2(C2H5)4N(1+)*Nb(CO)5H(2-)=[(C2H5)4N]2[Nb(CO)5H] → {Et4N}{(H)tetracarbonyl iron} (25879-01-0) + Nb(CO)5(C4H8O)(1-)*N(C2H5)4(1+)=Nb(CO)5(C4H8O)N(C2H5)4 + Fe(CO)4CHO(1-)*N(C2H5)4(1+)=Fe(CO)4CHON(C2H5)4

Guidance literature:

In tetrahydrofuran; at -50°C;

DOI:10.1021/ja00329a070

upstream raw materials:

methanol

iron pentacarbonyl

tetraethylammonium bromide

Downstream raw materials:

2{P(C₆H₅)4}⁽¹⁺⁾*HFe₃Ir^(2-)*12CO={P(C₆H₅)4}2*{HFe₃Ir(CO)12}

cyclopentadienyl iron(II) dicarbonyl dimer

[Fe2(μ-C(H)Bu(n))(μ-CO)(CO)2(.eta-C5H5)2]

(N(CH₂CH₃)4)⁽¹⁺⁾*(Fe(CO)4(Sn(C₆H₅)3))^(1-)={N(CH₂CH₃)4}{Fe(CO)4(Sn(C₆H₅)3)}

Refernces